半氧化锰矿湿法浸出过程及影响因素的分析.pdfVIP

本文还采用响应面法对影响半氧化锰矿浸出的因素进行分析，结果表 明，硫酸用量、葡萄糖用量、氟化铵用量和浸取时间这四个因素均对锰浸 出率影响极显著，它们的二次方对锰浸出率影响比较显著，硫酸用量和葡 萄糖用量之间的交互作用比较显著。氟化铵与葡萄糖在浸出反应过程中存 在着竞争氢离子的关系。响应面法获得的优化结果为：硫酸用量/矿量0.880 g·g-1、葡萄糖用量/矿量0.059 g·g-1、氟化铵用量/矿量0.04 g·g-1、浸取时间 6 h 。在此条件下，锰浸出率为 93.09%，而相同条件下，未加氟化铵时浸 出率为82.37%，表明添加氟化铵能明显改善锰矿的浸出效果。 关键词：半氧化锰矿 葡萄糖 氟化铵 浸出 II THE ANALYSIS OF LEACHING PROCESS AND FACTORS OF SEMI-OXIDIZED MANGANESE ORE ABSTRACT Manganese industry is always starting from leaching manganese sulfate which is the raw material of electrolytic manganese, manganese dioxide, manganese carbonate and manganese chloride products. With the development of manganese industry and manganese ore resources exploitation, high grade rhodochrosite and pyrolusite resources become increasingly tense, so the research of low grade ore especially semi-oxidized manganese ore has important economic value and prospective significance to alleviate this situation. In this paper, the leaching behaviour of semi-oxidized manganese ore was studied. The results showed that manganese leaching rate increases with the increase of dosage of reducing agent, the dosage of sulfuric acid and reaction temperature. Under low concentration of sulfuric acid, MnCO3 and MnO2 will be competition behavior of hydrogen ions, and MnCO3 is dominant. But the decomposition of MnO2 was conducive to the decomposition of MnCO3 which is wrapped in MnO . But under high concentration of sulfuric acid, this competition 2 behavior between them would no longer be apparent. On the mixed crystal simulation leaching experiments, MnCO3 and MnO2 of mixed crystal simulation could completely be leaching under the appropriate conditions. But even under the condition of high strength, semi-oxidized man