改质沥青煤焦油粘结剂添加B4C对铝用炭间糊性能的影响.DOCVIP

改质沥青煤焦油粘结剂添加B4C对铝用炭间糊性能的影响 刘卫1,2,3，姚桢1,2，陈毅1 （1.贵州师范大学 材料与建筑工程学院贵阳 550025；2.贵州省铝电解炭素材料工程技术研究中心贵阳 550025；3.贵州省教育厅无机非金属功能材料重点贵阳550025） 摘要：以改质沥青煤焦油混合粘结剂为基体，添加B4C制备改性粘结剂，并以电煅无烟煤、沥青焦、熟碎为骨料和改性粘结剂制备铝电解用炭间糊，研究B4C添加量对制备炭间糊性能及微观结构的影响。结果表明，随着B4C添加量的增加，制备炭间糊的灰分、电阻率、耐压强度、残炭率逐渐增大，挥发分、膨胀/收缩率、失重速率逐渐减小；B4C在高温下与O2、CO等小分子化合物发生化学反应，生成的氧化硼高温熔融，可以有效减缓粘结剂热解缩聚产生的体积变化和快速失重，并改善粘结焦的致密程度；当B4C添加量为3%时，制备炭间糊具有较佳的综合性能。 关键词：炭间糊；B4C添加量；膨胀/收缩过程；混合粘结剂；氧化硼TF821 文献标志码：A 文章编号：1007-7545（2017）10-0000-00 Effect of Modified Pitch-Coal Tar Mixed Binder with B4C on Properties of Ramming Paste for Aluminum Electrolysis LIU Wei1,2,3, YAO Zhen1,2, CHEN Yi1,2 （1. College of Material and Civil Engineering, Guizhou Normal University, Guiyan 550025, China; 2. Guizhou Engineering Research Center for Carbon Materials of Aluminum Electrolysis, Guiyang 550025, China; 3. Guizhou Key Laboratory of Inorganic Nonmetal Function Materials, Guiyang 550025, China） AbstractModified binder consists of modified pitch and coal tar mixed with boron carbide powders. Ramming paste was synthesized applying modified binder and calcined anthracite coal, coal derived pitch coke, baked scrap as aggregates. Effect of B4C addition on properties and microstructure of ramming paste were investigated. The results indicate that increasing addition of B4C, results in rises of ash, electrical resistivity, compressive strength and carbon yield, and drops of volatile matter and expansion/shrinkage. Obtained through high temperature chemical reaction between B4C and small molecular compounds such as O2, CO, B2O3 can reduce volume change and weight loss rate of ramming paste, and improve compact degree of binder coke. The optimal comprehensive properties of ramming paste are obtained with addition of B4C of 3%. Key words：ramming paste; B4C addition; expansion/shrinkage process; mixed binder; boron oxide 随着铝电解槽逐渐向大型化发展，其使用寿命已成为影响电解铝生产企业经济效益的重要因素之一[1]。在铝电解槽砌筑过程中，阴极炭块与炭块之间的缝隙采用炭间糊进行填充，炭间糊的性能关系着槽体在启动焙烧阶段的致密性以及铝液电解质的侵蚀程度，对铝电解槽的早期破损和使用寿命有直接的影响[2]。煤焦油作为炼焦工业