NaBi-硅酸盐学报.DOC

(NaBi)0.5–x(LiCe)xBi8Ti7O27陶瓷邵虹，江向平，(景德镇陶瓷学院材料科学与工程学院, , 江西省先进陶瓷重点实验室, 景德镇33300) 摘要(NaBi)0.5–x(LiCe)xBi8Ti7O27铋层状共生结构陶瓷，研究了陶瓷的结构与电性能。结果表明：所有(NaBi)0.5–x(LiCe)xBi8Ti7O27陶瓷样品均为共生结构，Li,Ce掺杂没有改变其固有结构；适量Li、Ce掺杂使样品晶粒尺寸均匀，且密度增加，达到ρ= 6.88 g/cm3；剩余极化强度Pr和压电常数d33均有显著提高，分别从4.19 μC/cm2和8 pC/N提高到8.39 μC/cm2和20 pC/N；在645 ℃和657 ℃处，样品介电温谱出现介电双峰；当x=0.时，样品最佳：d33 = 20 pC/N平面机电耦合系数= 8.86 %，厚度机电耦合系数= 15.15 %，机械品质因子Qm= 2 152，Pr = 8.39 μC/cm2。600 ℃退极化处理后，该组分d33仍有15 pC/N，表明该材料在高温领域具有良好的应用前景。 关键词：压电性能；介电性能；铁电性能 中图分类号：TQ174 文献标识码：A 文章编号：0454–5648(2015)09– – 网络出版时间： 网络出版地址： Electrical Properties of (NaBi)0.5–x (LiCe)xBi8Ti7O27 Ceramic SHAO Hong，JIANG Xiang-ping，FU Xiao-long，TU Na，LI Xiao-hong，YANG Fan，XU Xin-min，XIONG Shan (Jiangxi Key Laboratory of Advanced Ceramic Materials, National Engineering Research Center for Domestic and Buliding Ceramics, Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, Jiangxi, China) Abstract: The intergrowth bismuth layer-structured ceramic of (NaBi)0.5–x(LiCe)xBi8Ti7O27 was prepared by a solid-state reaction method. The microstructure and electrical properties of the samples were characterized. The results reveal that the (NaBi)0.5–x(LiCe)xBi8Ti7O27 material possesses intergrowth, and the structure does not change after the doping of Li/Ce. The proper content of Li/Ce substitute can increase the density of ceramic, and the maximum density is 6.88 g/cm3. The remanent polarization, Pr, and the piezoelectric constant value of the samples increase from 4.19 μC/cm2 to 8.39 μC/cm2 and from 8 pC/N to 20 pC/N, respectively. Two dielectric anomalies of Na0.5Bi8.5Ti7O27 occur at 645 ℃ and 657 ℃. When x = 0.25, the ceramic exhibits the optimum electrical properties, i.e., d33 = 20 pC/N, kp =8.86 %, kt = 14.11 %, Qm = 2 152, and Pr = 8.39 μC/cm2. The d33 of the component ceramic sample annealed at 600 ℃ is 15 pC/N, indicating that the ceramic is a promising material for the high-temperat