关于14C价态的选择-AMS.docVIP

Measuring 14C: 关于测量14C： HVEs 1.0 MV AMS tool in its standard configuration (without upgrade for lower background = without 2nd HE magnet) is designed to operate at charge state 2+. HVE的1.0MV 加速器质谱在它的标准配置（不需要升级为低背景=不需要第二级HE磁铁），被设计操作运行在charge state 2+。 HVE has built 15 of such 1.0 MV AMS systems and all users except NTU-Taipei measures 14C at charge state 2+?with high efficiency (fast measurments) and good background. NTU-Taipei is the only user that measures 14C at charge state 3+?which is far less efficient and therefor takes much longer time. ? HVE 已经建立了15个这样的1.0MV AMS系统，除了台湾大学之外的所有客户在测量14C时候都保持在电荷态charge state 2+，在此状态下效率高（快速测定）并且背景好。 。 As already explained in our email of 8 june 2017: 正如2017年6月份的邮件所述： From the publications already sent to IGCAS: 相关的测试报告 ·?????????A31180-01 Publ 2013 Klein NIMB - Extension of the HVE 1 MV Multi-Element AMS System for low background ·?????????A31180-01 Publ 2015 Heinemeier NIMB - The new extended HVE 1 MV multi-element AMS system for low background installed at the Aarhus AMS Dating Centre ·?????????A31180-01 Publ 2015 Hong - Radiocarbon measurement with 1 MV AMS at charge state 1+ it can be derived that Li interference is not an issue when operating at?14C2+?provided (i) the samples are prepared using the right method and (2) Cs with the right level of Li is used and (3) the system is tuned correctly. Li-6.94 从以上的文献可以看出，如果采用一下的方案时测量14C2+的时候Li的干扰不会是一个问题： （1） 样品使用了正确的方法； （2）Li的使用量和Cs的使用量在一个水平上； （3）系统调谐正确。 ? With such Upgrade the system can also be operated at?14C1+. Operating at?14C1+?fundamentally avoids any interference by lithium. 在升级系统中，将会测量14C1+ ， 操作?14C1+基本排除了Li的干扰。 In this case, the measurement background results from the stable carbon isotopes; and is dominated by?13C, which is closest in mass. 在这个情况下，测量的背景主要来自于稳定同位素离子，主要是13C，质量上很接近。 13C can reach the ion detector after (1) injection as molecule?13CH-, (2) dissociation in the stripper canal, (3) charge exchange in the HE tube resulting in an energy increase allowing to pas