低温等离子体促进烟气中单质汞氧化的特性分析-中国科学技术协会.PDF

30 卷 2 期 中 国 电 机 工 程 学 报 Vol.30 No.2 Jan.15, 2010 72 2010 年1 月15 日 Proceedings of the CSEE 20 10 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2010) 02-0072-05 中图分类号：X 701 文献标志码：A 学科分类号：470·10 低温等离子体促进烟气中单质汞氧化的特性分析 林文锋，张斌，侯文慧，周强，杨宏旻 ( 南京师范大学动力工程学院，江苏省 南京市 210042) Enhanced Oxidation of Elemental Mercury in Simulated Flue gas by Non-Thermal Plasma LIN Wen-feng, ZHANG Bin, HOU Wen-hui, ZHOU Qiang, YANG Hong-min (School of Power Engineering, Nanji ng Normal University, Nanji ng 210042, Jiangsu Province, China) ABSTRACT: A laboratory-scale system to measure the 对单质汞的氧化具有不利影响；在Hg/N /O /CO /H O 复杂 2 2 2 2 oxidation performance of the elemental mercury by non- 烟气氛围下，由于活性基团相互之间的制约，单质汞的氧化 thermal plasma (NTP) was set up and the effect of main gas 率平均为75%，在烟气中添加少量的HCl 会明显提高单质 constituents on the oxidation of elemental mercury under NTP 汞的氧化率。提出了在等离子体条件下 HCl 离解并氧化单 atmosphere was investigated experimentally. The results 质汞的机制。 indicate that the non-thermal plasma is a prospective approach 关键词：单质汞；低温等离子体；氧化增强；烟气氛围 to oxidize elemental mercury. The oxygen and water vapor promote the oxidation of elemental mercury significantly and 0 引言 1.5% oxygen and 4% water vapor can achieve 97.4% and 鉴于汞对人类健康和环境带来的威胁，汞污染 92.5% of the mercury oxidation efficiency respectively. Active [1-3] radicals generated b