(英)树脂负载离子液体萃取稀土金属钇.pdfVIP

Separation and Purification Technology 63 (2008) 61–68 Contents lists available at ScienceDirect Separation and Purification Technology j o u rn al h omepage: www.elsevi er.c om /locate/s eppur The solid–liquid extraction of yttrium from rare earths by solvent (ionic liquid) impreganated resin coupled with complexing method Xiaoqi Sun, Bo Peng, Yang Ji, Ji Chen ∗ , Deqian Li Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Renmin Street 5625, Changchun 130022, PR China a r t i c l e i n f o a b s t r a c t Article history: A kind of solvent (ionic liquid) impreganated resin (IL-SIR) was developed herein for ameliorating Received 2 January 2008 imidazolium-type IL-based liquid–liquid extraction of metal ions. In this study, [C8 mim][PF6 ] containing Received in revised form 30 March 2008 Cyanex923 was immobilized on XAD-7 resin for solid–liquid extraction of rare earth (RE). The solid–liquid Accepted 31 March 2008 extraction contributed to ameliorating mass transfer efficiency, i.e. shortening equilibrium time from 40 min to 20 min, increasing extraction efficiency from 29% to 80%. In additional, the novel IL-SIR could Keywords: separate Y(III) from Sc(III), Ho(III), Er(III), Yb(III) effectively by adding water-soluble complexing agent. Ionic liquid-based extraction Thus, the solid–liquid extraction by IL-SIR coupled