以水热法转化纤维素为具有附加价值化学品之研究conversionof.pdfVIP

臺灣鑛業，第 65 卷第 1 期，第 38-44頁，民國 102 年 3月 以水熱法轉化纖維素為具有附加價值化學品之研究 Conversion of Cellulose into Value-Added Chemicals by Hydrothermal Method 1 1 2, 王敬中 賴榕樺 林仁斌 * Jing-Jung Wang 1 , Rong-Hua Lai 1 , Ren-Bin Lin 2 摘 要 本研究以水熱法將纖維素轉化為具有附加價值之化學品（e.g. 葡萄糖、 5-羥甲基糠醛 (5-HMF) ），探討球磨前處理與水熱反應條件（180~240℃，22~24 bar ）對纖維素轉化反應產物 之產率的影響。研究結果顯示經過球磨處理 72 小時後，纖維素的結晶度由原先的 72%減少為 20% 。經球磨處理72 小時的纖維素在溫度220℃與壓力 22 bar條件下反應 1 小時後的葡萄糖與 5-HMF 產率可分別由 2.9 、10.5%提昇至 11.5 、34.0% ；然而隨著反應時間的增長，這兩者的產 率皆隨之降低，反應時間至 12 小時後的葡萄糖與5-HMF 產率已分別減少為 0.3 、4.4% ，這顯示 最初反應生成的葡萄糖與 5-HMF已進一步轉化為其他副產物。本研究結果可作為纖維素水熱轉 化製程開發之基礎資料。 關鍵詞：纖維素、水熱法、球磨法、5-羥甲基糠醛、生質能。 Abstract In this work, the cellulose was converted into value-added chemicals (e.g. glucose, 5-hydroxymethylfurfural (5-HMF)) by the hydrothermal method. The effects of the ball-milling pretreatment and the hydrothermal reaction conditions (180~240℃, 22~24 bar) on the product yields of TAO cellulose conversion were investigated. The results showed that the crystallinity index of raw cellulose (72%) was reduced to 20% after a 72 hr of ball-milling. For 1 hr of reaction time under the hydrothermal condition (220℃, 22 bar), the yields of glucose and 5-HMF of the 72 hr ball-milled cellulose were respectively promoted to 11.5% and 34.0% comparing to those (2.9% and 10.5%) for the raw cellulose. Nevertheless, the yields of both the glucose and