铋含量对铅铋合金析氧行为影响.pdfVIP

电 源 技 术 研 究 与 设 计 秘含量对铅秘合金析氧行为的影响 龙 雪梅 ，李伟善 （广州华南师范大学 化学系，广东 广州 510631 割 摘要 ：制备了铅含量为0~7.33% （质量百分数 ）的铅铅合金。 用线性电位扫描、交流阻抗法以及气体收集实验研究了铅 铅合金在硫酸溶液中的析氧行为，确定了相关的电化学动力学参数。 研究结果表明，当铅铅合金中铅含量小于 0. 100% 时，铅的存在对析氧反应几乎无影响，而当铅含量大于 0.83%时，铅加快氧气的析出，且随铅含量增加，析氧过电位降 低，电荷交换反应电阻减小，析氧量增加。 关键词 ：铅酸蓄电池；铅铅合金; 析氧动力学; 交流阻抗 中图分类号 ：TM 9 12.1 文献标识码 ：A 文章编号 ：1002-087 X （2004 ）09-0575-03 Effect of bismuth content on oxygen evolution behaviors of lead-bismuth alloy in sulphuric acid solution LONG Xue-mei, LI Wei-shan (Dep artment of chemistry , South China Normal University , Guangzhou Guangdong 51063 1,China) zLead-bismuth alloys with Bi content from 0 to 7.33% are prepared. The oxygen evolution behavior on the prepared lead-bismuth alloys in sulphuric acid solution are studied by liner sweep voltammetry, measurement of the volume of oxygen evolution and alternative current impedance. When the Bi content in the lead-bismuth alloy is lower than 0.10%, there is no significant difference in oxygen evolution on lead-bismuth alloys and lead. However, when the Bi content in the alloy is higher than 0.83% , the effect of bismuth on oxygen evolution on lead-bismuth appearsz the overpotential and the electron transfer resistance decrease and oxygen evolution volume increasees with increasing Bi content in the alloys. zlead-acid battery ;lead-bismuth alloys; oxygen evolution kinetic; alternative current impedance 为了满足铅酸蓄电池的少维护和免维护性能要求， 传统 1 实验 的铅锑合金逐渐被低锑合金或无锑合金所取代。 然而锑的除