天然橡胶分子链侧链结构的表征.pdfVIP

第31 卷 第5 期 Vol. 31 No. 5 2017 年5 月 CHINESE JOURNAL OF MATERIALS RESEARCH May 2017 天然橡胶分子链侧链结构的表征 金林赫 蔡婧宜 张会丰 廖双泉 (海南大学材料与化工学院 热带岛屿资源先进材料教育部重点实验室 海口 570228) 摘要使用氮标记法以及凝胶渗透色谱仪、凯氏定氮仪、傅里叶红外光谱仪、核磁共振波谱仪等手段，分析和表 征了天然橡胶分子链侧链中环氧基、醛基、羧基、羟基和分子链中的3,4-聚合结构。结果表明：在天然橡胶分子 链侧链中，环氧基含量为0.63% ，羟基含量为0.04% ，醛基含量为0.11% ，羧基含量为0.01% 。根据上述结果，构 建了天然橡胶分子链侧的链结构模型。 关键词 有机高分子材料，天然橡胶，分子链，支链结构，分析 中图分类号 TQ331.2 文章编号 1005-3093(2017)05-0369-05 Structural Characterization of Natural Rubber Molecular Side Chain JIN Linhe, CAI Jingyi, ZHANG Huifeng, LIAO Shuangquan (College of Material and Chemical Engineering, Hainan University, Key Laboratory Advanced Materials of Tropical Island Resources, Ministry of Education, Haikou 570228, China) Correspondent: LIAO Shuangquan, Tel: (0898 E-mail: shqliao@263.net Supported by National Natural Science Foundation of China (No.; Special Fund for Agro-scientific Re- search in the Public Interest (No.; Science and Technology Program of Hainan (No. ZD- KJ2016020-02) Manuscript received 2016-11-01, in revised form 2017-02-12 ABSTRACT The branch Side-chains of the natural rubber molecular chain are investigated in this the- sis. The instruments such as by means of Gel Permeation Chromatograph (GPC), Kjeldahl Auto Analyz- er, Fourier Transform Infrared Spectrometer(FTIR) and Nuclear Magnetic Resonance(NMR) Spectrome- ter etc. in terms of the epoxide group, hydroxyl, aldehyde