环戊烷制备方法.docVIP

一种环戊烷的制备方法 发明人: 万书晓;汪孟言;叶岗;陈亚军摘要: 一种由双环戊二烯连续解聚、加氢制备环戊烷的方法,是在0.1~2.5MPa的系统压力下,在氢气和稀释剂的存在下,将双环戊二烯在160~400的解聚器中解聚为环戊二烯,将环戊二烯在10~100的装有换热装置的固定床反应器中加氢为环戊烷,并收集环戊烷.该方法可使解聚、加氢两步反应连续进行,提高了双环戊二烯的解聚率,环戊烷的收率也明显提高,可达70%以上,而且延长了催化剂的使用寿命.Desulfidation Process of Cyclopentane Sulfides are principal impurities in cyclopentane,and seriously affect the color and stress of polyurethane products.A process has been investigated with N-formylmorpholine as extractant to remove sulfides in cyclopentane produced from the light hydrocarbons of oil field.The optimal operating conditions are V(N-formylmorpholine)∶V(cyclopentane)=1.03∶1.00,w(N-formylmorpholine)≥95%,temperature 25~38 ℃,low pressure extraction and atmospheric pressure regeneration.The pilot plant results are as follows.Yield of cyclopentane is 93.7% and the consume of N-formylmorpholine is 2.0 kg/t according to 9.38 μmol/L of the sulfides content in cyclopentane.This technique shows its potential industrial prospect in deep processing of light hydrocarbons from the oil field. 对以双环戊二烯为原料,经解聚、加氢制备环戊烷的工艺进行了研究,重点考察了环戊二烯加氢条件.结果表明:在Raney镍催化剂加入量为0.5%~2%,加氢压力为0.5~3.0MPa,加氢温度为30~50℃时,环戊二烯的加氢转化率约为100%,加氢选择性也在99%以上,由双环戊二烯制备环戊烷的总收率gt;60%,产品的纯度在99%以上. 【分类号】:TQ231.13 【DOI】:cnki:ISSN:1004-017X.0.2003-06-007 【正文快照】: 1前言 环戊烷作为CFC的理想替代品,被广泛地用作电冰箱、冰柜的保温材料及其他硬质PU泡沫的发泡剂.世界发达国家如德国、美国、英国已率先在冰箱及PU行业实现了无氟化.我国已在保护大气臭氧层的蒙特利尔公约上签字,随着该公约执行期限的临近,国内大部分冰箱厂、聚氨醋厂及研究机构都在寻找CFC的合适替代品.我国无氟冰箱年产量已达800万台,环戊烷年需求量将达5000吨以上,特别是高纯度环戊烷国内目前尚无法生产. 生产环戊烷的工艺有多种,其中最直接的方法是从沸程为30一60℃的石油醚中提取.由于其含量仅为5%一10%,约需处理10~20吨才… CAJViewer7.0阅读器支持所有CNKI文件格式,AdobeReader仅支持PDF格式 Preparation of Cyclopentane from Dicyclopentadiene The studies on preparation of cyclopentane by depolymerization of dicyclopentadiene and hydrogenation of cyclopentadiene were carried out. The conversion of hydrogenation of cyclopentadiene are almost 100% , and the selectivity to cyclopentane is also above 99% in the presence of Raney nickel catalyst at a reaction temperature of 30 to 50℃, the hydrogen pressure of 0. 5 t