水滑石前体法制备CoAl2O4 石墨烯气凝胶作为双功能电催化剂.pdfVIP

Journal of Advances in Physical Chemistry 物理化学进展, 2017, 6(3), 113-120 Published Online August 2017 in Hans. /journal/japc /10.12677/japc.2017.63014 CoAl O /Graphene Aerogel by 2 4 Hydrotalcite Precursor Method as Bifunctional Electrocatalysts Cong Zhang, Ge Meng* State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing nd th st Received: Jul. 2 , 2017; accepted: Jul. 15 , 2017; published: Jul. 21 , 2017 Abstract Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are critical paired reac- tions for both energy conversion and storage. Recently, the research on electrocatalysts for OER/ ORR has been focused on the study of easy, cost-effective, and highly active composites as poten- tial alternatives to the precious metal materials (such as Pt, Ru, Ir). In this work, cobalt-aluminum hydrotalcite/graphene aerogels (CoAl-LDH/GA) were fabricated via a facile hydrothermal process, using the electrostatic interaction of single cobalt aluminum hydrotalcite (CoAl-LDH) and gra- phene oxide (GO). After high temperature calcination process, the cobalt aluminum oxide/gra- phene aerogel composites (CoAl O /GA) were obtained. The surface properties, microstructure 2 4 pore size, element content and crystalline phase of the prepared products had been characterized by means of SEM, TEM and XRD, respectively. Results showed that the best catalyst exhibited high activity, which was close to commercial Pt/C and Ir/C catalysts, while the cycle stability was much higher than the commercial one. Therefore, the CoAl O /GA composite material was a per