锰矿含碳团块高温熔融自还原试验研究.pdfVIP

锰矿含碳团块高温熔融自还原试验研究 ·1 · 锰矿含碳团块高温熔融自还原试验研究 张 波 胡洵璞 高泽平 王大萍 苏振江1 （湖南工业大学冶金工程学院，湖南株洲 412007 ） 摘 要 本文采用湖南贫锰矿为主要原料，在高温碳管炉内进行锰矿含碳团块高温熔融自还原试验，试验温度控制 在1550~1650℃，对影响团块还原度的主要因素进行分析，并对还原过程中金属Mn 的挥发情况进行计算。结果表 明：锰矿自还原团块内C/O 最佳值为1.2，当C/O＜1.2 时，团块内还原剂量不够，团块还原度较低，而当C/O≥1.2 时，团块内还原剂出现过剩，多余的还原剂对团块还原度的提高没有明显作用；还原温度的提高可促进团块还原度 增加，但变化幅度不大；助熔剂CaF2 可降低团块熔点和黏度，加快团块在前期的还原；金属Mn 的挥发呈抛物线 状，反应前期挥发量较大，而随着反应的进行，由于液渣量的增加，阻隔了金属Mn 的向外扩散，金属Mn 的挥发 量逐渐减少。提高液渣的形成速度是抑制金属Mn 挥发的有效途径。 关键词 锰矿含碳团块，高温，熔融自还原 Study on the Melting Self-reduction Behavior of Manganese Ore Briquette Containing Carbon at High Temperature Zhang Bo, Hu Xunpu, Gao Zeping, Wang Daping, Su Zhenjiang (College of Metallurgy, Hunan University of Technology, Zhuzhou 412007, China) Abstract Use the lean manganese ore in Hunan province as main raw materials, the self-reduction experiment of manganeseore briquette containing carbon was carried out in the high-temperature carbon tube furnace, and the reduction temperature is 1550~1650 ℃. The main factors affecting the reduction rate were analyzed, and the volatilization of Mn is calculated in the process of reduction. The results show that the optimal value of C/O in briquette is 1.2, when the C/O ＜1.2, the amount of reductant is not enough and the reduction degree of briquette is low, and if the C/O ≥1.2, the amount of reductant is excess has no obvious effect for improve the reduction degree of briquette;The increase of reduction temperature has effect on improvement of reduction degree, but the effect is not obvious; It can accelerate reduction and decrease reduction time when the appropriate flux CaF2 is added to the briq