矿渣–粉煤灰混合材料水化产物微观结构和性能-硅酸盐学报.PDFVIP

第 35 卷第 5 期 金松哲等：低温合成 Ti SiC 陶瓷 · 633 · 3 2 第 35 卷第 5 期 硅 酸 盐 学 报 Vol. 35 ，No. 5 2 0 0 7 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY M a y ， 2 0 0 7 矿渣–粉煤灰混合材料水化产物、微观结构和性能 张景富，丁 虹，代 奎，孙 超 (大庆石油学院，提高油气采收率教育部重点实验室，黑龙江 大庆 163318) 摘 要：用 X 射线衍射仪和扫描电子显微镜等对矿渣、粉煤灰混合材料的水化产物、硬化体微观结构及强度进行了检测和分析，确定了水化产物的 组成及微观结构特点，揭示了矿渣粉煤灰材料的水化作用特点及强度特征。结果表明：矿渣在激发剂作用下使玻璃体首先发生表面水解，产生水化反 应，进而引发粉煤灰的火山灰作用；混合材料的水化产物组分以水化硅酸钙凝胶为主，硬化体具有与油井水泥相类似的网络状微观结构；随养护时间 增长，混合材料后期强度持续增加。 关键词：矿渣；粉煤灰；水化产物；微观结构；强度 中图分类号：TQ172.4+4 ；TE256 文献标识码：A 文章编号：0454–5648(2007)05–0633–05 MICROSTRUCTURE AND PROPERTIES OF HYDRATION PRODUCTS OF SLAG-FLY ASH MIXED CEMENTITIOUS MATERIALS ZHANG Jingfu ，DING Hong ，DAI Kui ，SUN Chao (Enhanced Oil and Gas Recovery Key Laboratory of Ministry of Education, Daqing Petroleum Institute, Daqing 163318, Heilongjiong, China) Abstract: The hydration products, microstructure and strength of slag–fly ash mixed cementitious materials were measured and ana- lyzed by X-ray diffraction and scanning electron microscopy. The composition and microstructure of the hydration products were determined, and the hydration and strength characteristics of slag–fly ash mixed cementitious materials were studied. The results in- dicate that under the action of an excitation agent, surface hydrolysis of slag takes place on the glass body first and the hydration reac- tion occurs. Then the pozzolanic reaction of fly ash takes place. The main compositions of hydration products for slag–fly ash mixed cementitious materials