毕业论文（设计）改进的McAllister三体模型用于推算二元混合物的黏度.docxVIP

改进的McAllister三体模型用于推算二元混合物的黏度摘要：McAllister三体模型被普遍认为是针对液体二元混合物运动黏度的最佳关联式。本文对McAllister三体模型进行了研究，在对三类（醇类/醇类、烷烃/醇类、烷烃/烷烃）二元混合物的黏度数据进行文献搜集和整理的基础上，发现模型中的相互作用参数（ν12和ν21）随二元混合物的等效分子量和温度呈现出规律性的变化。因此，本文建立了一种改进的McAllister三体模型，并对乙醇与丙醇、丁醇、戊醇、己醇、庚醇、辛醇、壬醇、癸醇体系，异辛烷与丙醇、己醇、戊醇、辛醇体系，正丁基环己烷与庚烷、辛烷、壬烷、癸烷、十二烷、十四烷体系的黏度进行了推算，计算结果表明，计算值与实验值的总体平均绝对偏差为1.00%，最大偏差为9.75%。关键词：McAllister三体模型；乙醇+醇类；正丁基环己烷+烷烃类；异辛烷+醇类Improved McAllister Three-Body Model to Calculate Viscosities of Binary MixturesWANG Xiao-jie, LANG Han-xiao, MA Qian, WANG Xiao-po*(Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xian Jiaotong University, Xi’an, Shanxi 710049, China)Abstract McAllister three-body model is generally regarded as the best correlation for the kinematic viscosities of binary liquid systems. In this work, McAllister three-body model was proposed based on the viscosity data of three types of binary mixtures (alcohols/alcohols, alkanes/alkanes, alkanes/alcohols). We found that the model interaction parameters (ν12 and ν21) exhibit regular trends along with equivalent molecular weights of binary mixtures and temperatures. Therefore, an improved McAllister three-body model was proposed. The new model was used to calculate the viscosities of different binary mixtures, including ethanol + 1-propanol, + 1-butanol, + 1-pentanol, + 1-hexanol, + 1-heptanol, + 1-octanol, + 1-nonanol, and + 1-decanol systems, n-butylcyclohexane + 1-heptane, + 1-octane, + 1-nonane, + 1-decane, + 1-dodecane, and + 1-tetradecane systems, and 2,2,4-Trimethylpentane+1-propanol, +1-pentanol, + 1-hexanol, and +1-heptanol systems. The results show that the overall average absolute deviation is 1.00% between the calculated data and experimental values, and the maximum deviation is 9.75%.Keywords McAllister three-body model; ethanol/1-alcohols; n-butylcyclohexane/1-alkanes; 2,2,4-trimethylpentane /1-alcohols0. 引言黏度是用于描述流体流动阻力的一种基本属性，液体混合物的黏度对于流动系统的研究尤为重要，比如原油开采和运输[1]，纳米流体科学[2]，食品工程[3]，冶金制造过程[4]等。由于液体混合物的黏度测量极其耗费时间，因此