低合金钢和碳钢在90℃地下水模拟溶液中的缝隙腐蚀.PDFVIP

第50 卷 第6 期 Vol.50 No.6 2014 年6 月 第659-666 页 ACTA METALLURGICA SINICA Jun. 2014 pp.659-666 低合金钢和碳钢在90 ℃地下水模拟溶液中 的缝隙腐蚀* 徐秋发 庞晓露 刘泉林 高克玮 (北京科技大学材料物理与化学系, 北京 100083) 摘 要 利用浸泡实验与电化学实验研究了低合金耐候钢Corten A 和碳钢Q235 在90 ℃地下水模拟溶液中的缝隙腐蚀行 为. 采用SEM, EDS 和Raman 光谱分析了缝内腐蚀产物膜的形貌和成分. 结果表明, 2 种钢均发生了缝隙腐蚀, 且随着腐蚀 时间的延长缝隙腐蚀越严重; Corten A 的缝隙腐蚀比Q235 严重; 在中性或偏酸性的溶液中, 耐候钢的耐腐蚀性能优于碳钢, 而在pH 值为1 的溶液中, 耐蚀性则相反; 合金元素Cr, Cu 和Si 对Corten A 在溶液中的耐缝隙腐蚀性能不利. 关键词 高放废物, 地下水, 低合金钢, 碳钢, 缝隙腐蚀 中图法分类号 TG 172.3 文献标识码 A 文章编号 0412-1961(2014)06-0659-08 CREVICE CORROSION OF LOW ALLOY STEEL AND CARBON STEEL IN THE SIMULATED GROUNDWATER AT 90 ℃ XU Qiufa, PANG Xiaolu, LIU Quanlin, GAO Kewei School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 Correspondent: GAO Kewei, professor, Tel: (010) E-mail: kwgao@mater.ustb.edu.cn Supported by National Natural Science Foundation of China (No Manuscript received 2014-01-13, in revised form 2014-03-08 ABSTRACT Carbon steel and low alloy steel as candidates of high-level radioactive waste packaging materials, will undergo groundwater corrosion during long term disposal in underground repository, so it is necessary to study the corrosion behaviors of carbon steel and low alloy steel in the specific environment. Crevice corrosion behaviors of carbon steel Q235 and low alloy weathering steel Corten A were studied in a simulated groundwater at 90 ℃ through immersion tests and electrochemical measurements. SEM, EDS and Raman spectra were employed to ana- lyze the corrosion product