碳钢的阳极极化过程研究.pdfVIP

碳钢的阳极极化过程研究 ·1 · 碳钢的阳极极化过程研究 1 1 1 1 2 2 1 陈海林 贺立红 邵远敬 叶理德 王英英 夏先平 蔡 炜 （1. 中冶南方工程技术有限公司技术研究院；2. 华中科技大学材料学院） 摘 要 用线性电位扫描法研究了碳钢在不同浓度电解质条件下的阳极极化过程，再进一步用恒电位法、恒电流法 分别研究了碳钢在不同浓度电解质条件下电解行为。发现碳钢阳极极化过程依次经历活化区、钝化区、过钝化区及 极限区，不存在活化-钝化过渡区；在过钝化区电极表面发生析氧反应，使得阳极电流呈指数增加；当阳极电流达 到最大值后开始降低并最终稳定在某个范围内，电极表面进入极限区，除继续发生析氧反应外，还会发生基体溶解 反应，并在电极表面覆盖大量氧化产物；进一步分析发现，电解质浓度越低，电位越高，基体溶解反应越容易进行， 而极限区的存在是由于OH－离子存在浓度极限。 关键词 碳钢，过钝化，恒电位 The research of Anodic Polarization Process of Carbon Steel in Alkali Solution 1 1 1 1 2 2 1 Chen Hailin , He Lihong , Shao Yuanjing , Ye Lide , Wang Yingying , Xia Xianping , Cai Wei (1. Technolegy Research Division of WISDRI Engineering Research Incorporation Limiited Wuhan, China; 2. Huazhong University of Science and Technology, Wuhan, China) Abstract Anodic polarization process of carbon steel in solution was studied by linear potential scan.Electrolysis behavior was also analyzed under differential electrolyte concentration and differential electric potential or current by electrolysis at constant potential or current. They were found that anodic polarization process of carbon steel in solution included activated region, passive region, transpassive region, and terminal region except of transition zone between activated and passive. In transpassive region, oxygen evolution reaction which caused that anodic current increased sharply occurred on the electrode surface