耦合膜分离和电吸附的复合功能膜处理cuⅱ废水-环境工程学报.pdfVIP

第 11卷　 第7 期 环 境 工 程 学 报 Vol. 11,No.7 2 0 1 7 年 7 月 Chinese Journal of Environmental Engineering July 2 0 1 7 耦合膜分离和电吸附的复合功能膜处理Cu(Ⅱ) 废水 ∗ 李子梦,于鸿光,王志伟 ,吴志超 同济大学环境科学与工程学院,上海 200092 摘　 要　 提出了一种膜分离和电吸附耦合的导电复合膜工艺对含 Cu(Ⅱ)废水进行处理,采用自制复合膜研究了外加电 压、膜通量和进水 Cu(Ⅱ) 浓度等条件对复合膜吸附去除 Cu(Ⅱ)的影响。 结果表明,在外加电压 0 ~ 1.6 V、膜通量 8 ~ 2 -1 40 L ·(m ·h) 的条件下,电压越大,膜通量越小,总溶解性固体(TDS)去除率越大;膜通量越大,TDS 吸附量越大。 在 -1 Cu(Ⅱ) 浓度5 ~40 mg ·L 的条件下,Cu(Ⅱ) 浓度越大,TDS去除率越小,而吸附量越大。 不同工况条件下,跨膜压差均 维持在较低水平。 本研究为重金属废水的处理提供了新思路。 关键词　 重金属去除;膜分离;电吸附;废水处理 中图分类号　 TQ127.1　　 文献标识码　 A　　 文章编号　 1673-9108(2017)07-4017-06　　 DOI:10.12030/ j.cjee.201605206 Cu( Ⅱ) removal using a composite functional membrane process coupling membrane separation and electrosorption ∗ LI Zimeng,YU Hongguang,WANG Zhiwei ,WU Zhichao School of Environmental Science and Engineering,Tongji University,Shanghai 200092,China Abstract　 In the present study,a conductive composite membrane process,coupling membrane separation,and electrosorption were developed for Cu(Ⅱ) removal. The effects of applied voltage,flux,and feed Cu(Ⅱ) con- centration on the system performance were investigated using self-made composite membrane modules. Results -2 -1 showed that when the applied voltages and flux were within the range 0-1.6 V and 8-40 L ·m ·h ,respec- tively,the removal ratesof total dissolved solids (TDS)were higher with larger applied voltages and smallerflux, -1 and TDS adsorption amounts increased with flux. At feed Cu(Ⅱ) concentration of 5-40 mg ·L ,the TDS re- moval rates decreased. TDS adsorption amounts increased at higher Cu(Ⅱ) concentrations. Transmembrane pr