两亲性嵌段共聚物PS-b-PMAA的合成与胶束化行为研究Studyon.PDF

2005 年第 63 卷 化 学 学 报 Vol. 63, 2005 第 7 期, 631～636 ACTA CHIMICA SINICA No. 7, 631～636 ·研究论文· 两亲性嵌段共聚物 PS-b-PMAA 的合成与胶束化行为研究 华 慢 杨 伟 薛 乔 陈明清* 刘晓亚 杨 成 (江南大学化学与材料工程学院 无锡 214036) 摘要 利用原子转移自由基聚合法(ATRP)得到了分子量可控、分子量分布接近 1.1 的聚苯乙烯-b-聚甲基丙烯酸叔丁酯 (PS-b-PtBMA)嵌段共聚物, 进而在酸性条件下由水解反应得到了两亲性的聚苯乙烯-b-聚甲基丙烯酸 (PS-b-PMAA)嵌 段共聚物．用 GPC, FTIR 和 1H-NMR 等对产物的分子量和组成进行了表征．使 PS-b-PMAA 在选择性溶剂中进行自组 装, 通过激光光散射和透射电子显微镜研究了影响其胶束化行为的因素与胶束形态, 并初步探讨了胶束形成的机理, 发现通过控制嵌段共聚物的链段长度之比可得到空心球形的高分子胶束． 关键词 原子转移自由基聚合; 两亲性嵌段共聚物; 胶束化; 空心球形胶束 Study on Synthesis of Amphiphilic PS-b-PMAA and Their Micellization HUA, Man YANG, Wei XUE, Qiao CHEN, Ming-Qing* LIU, Xiao-Ya YANG, Cheng (School of Chemical and Material Engineering, Southern Yangtze University, Wuxi 214036) Abstract Atom transfer radical polymerization (ATRP) is a kind of useful method for synthesis of block copolymers. The block copolymers of poly(styrene)-block-poly(tert-butyl methacrylate) (PS-b-PtBMA) were synthesized by ATRP method. Then the amphiphilic block copolymers of poly(styrene)-block-poly- (methyl acrylic acid) (PS-b-PMAA) were obtained by hydrolysis from PS-b-PtBMA copolymers in HCl so- 1 lution. Furthermore, the copolymer products were characterized by using GPC, FTIR and H NMR. Various factors that influence micellization of amphiphilic bloc