材料合成化学课件(3-2A) Metal synthesis (color).pdf

Chapter 3-2: Synthesis of metal nanoparticles and films • 3.2.1 Introduction • 3.2.2 Theory: nucleation-seed-nanocrystals • 3.2.3 Chemical reduction method: (synthesis of Au and bi-metallic nanoparticles) • 3.2.4 Electrochemical reduction • 3.2.5 Hydrothermal • 3.2.6 Photochemical • 3.2.7 Sonochemical • 3.2.8 Chemical Vapor Deposition • 3.2.9 Physical Vapor Deposition (Vacuum evaporation) Keyword : Reduction • 3.2.10 Case study “金属制备并不难，看你怎样去还原” 3.2.1 Introduction Nanomaterials is not new… nanoscience is. TEM Analysis top: TEM of 4 nm Au – light pink top: TEM of 4 nm Au – light pink Chi’en Lung Dynasty (1736-96) bottom: TEM of 30 nm Au – deep red Chi’en Lung Dynasty (1736-96) bottom: TEM of 30 nm Au – deep red Gold nanospheres with increasing diameter size Bulk Au 4 nm 12 nm 25 nm 37 nm • Optical properties of metal nanoparticles depend on their shape and size • Particle functionalization can be done on the surface • Visible optical changes occur Michael Faraday 1791-09-22 – 1867-08-25 (aged 75) Residence: England Nationality: British Fields: Physics and Chemistry Institutions: Royal Institution Known for: Faradays law of induction Electrochemistry Faraday effect Portrait by Henry Willia