聚醚共聚酰胺PEBA膜的溶胀和渗透汽化行为研究-高校化学工程学报.PDFVIP

第24 卷第1 期 高 校 化 学 工 程 学 报 No.1 Vol.24 2010 年 2 月 Journal of Chemical Engineering of Chinese Universities Feb. 2010 文章编号：1003-9015(2010)01-0016-06 聚醚共聚酰胺(PEBA)膜的溶胀和渗透汽化行为研究 刘 琨, 杨 超, 陈 松, 邹 昀 (广西大学 化学化工学院, 广西 南宁 530004) 摘 要：用涂布法制备出PEBA均质膜，分别测试了膜在纯醋酸正丁酯、水以及醋酸正丁酯稀水溶液中的溶胀率，并考 察了浸泡时间、温度和溶液浓度对溶胀率的影响；结果表明：PEBA膜在水中溶胀很小，对醋酸正丁酯具有优先吸附能 力；溶胀率随浸泡时间的延长、浸泡液浓度和温度的升高而逐渐上升。渗透汽化实验表明膜对醋酸正丁酯的良好选择 性，膜的渗透通量和分离因子随着浓度的增加而增加，渗透通量随着温度的升高而增加，但分离因子随温度的升高而 减小；当原料液浓度为0.6%(wt)时，醋酸正丁酯的渗透通量为143.9 g⋅m−2 ⋅h− 1，分离因子达到 236.9 。 关键词：聚醚共聚酰胺(PEBA)；膜；溶胀；渗透汽化 中图分类号：TB383 ；TQ028.16 文献标识码：A Swelling and Pervaporation Behavior of Poly(ether block amide) Membrane LIU Kun, YANG Chao, CHEN Song, ZOU Yun (School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China) Abstract: The poly(ether block amid) (PEBA) membrane was prepared by solvent casting method. The swelling behaviors of the prepared membrane in pure n-butyl acetate, water and n-butyl acetate aqueous solution were explored respectively. The effects of n-butyl acetate concentration, dipping time and temperature on the swelling degree of the prepared membrane were investigated respectively. The results indicate that the swelling degree of the prepared membrane increases with increasing the n-butyl acetate concentration, dipping temperature and time, respectively. In addition, experiments of n-butyl acetate removal from its aqueous solution through pervaporation (PV) by the prepared membrane were conducted, and the influences of n-butyl acetate concentration and operating temperature on the PV performance of the prepared membrane wer