PVC用新型钙-锌复合热稳定剂探究.docVIP

PVC用新型钙/锌复合热稳定剂探究 　　【摘 要】本文采用变色法对聚氯乙烯（PVC）用新型钙/锌复合热稳定剂的性能进行了研究，得到了PVC用新型高效钙/锌复合热稳定剂的实用配方，并与市场常用的几种稳定剂进行了静态、动态热稳定性比较。结果表明，硬脂酸钙与硬脂酸锌的比例对PVC材料的初期色泽和长期热稳定性有较大影响，二者比例为1/1.5时性能最佳，新郑庆宏化工有限公司所研制的QH-06型钙锌复合热稳定剂有较好的协同作用，与进口钙/锌稳定剂性能相近，使用QH-06型钙锌复合热稳定剂的PVC试样的塑化流变性良好，在不改变PVC加工工艺的条件下可以替代其他几种热稳定剂。 【关键词】聚氯乙烯（PVC）；热稳定剂；协同作用；硬脂酸钙；硬脂酸锌 Study on A Novel Ca/Zn Compound Thermal Stabilizer for Rigid PVC XIE Yao-chen1 WANG Jian-jun2 （1.Zhongyuan University of Technology，Xinzheng Henan 451150；2.XingZheng QingHong Chemical Co.Ltd. Xinzheng Henan 451150） 【Abstract】In this paper，the thermal stabilizer of Ca/Zn compound for PVC was studied by the method of discoloration，obtaining practical formula of new tape thermal stabilizer of Ca/Zn compound for PVC.And that was compared with several thermal stabilizers that was common used in the aspect of static and dyna.micthermal stability.The results showed that the proportions of calcium stearate and zincstearate had a great influence in initial color and long-term thermal stability of PVC. It would be in best property when both stearates were at the ratio of1/1.5.QH-06thermal stabilizer of Ca/Zn compound that was manufactured by XingZheng QingHong Chemical Co.Ltd had preferable synergistic effect，which was similar to import thermal stabilizers.The sample of PVC by using QH-06 thermal stabilizer of Ca/Zn compound had Plasticizingrheologicalproperty.And it can take place of several otherthermal stabilizers in the condition of not changing the processing craft of PVC. 【Key words】Polyvinyl chloride（PVC）； Thermal stabilizer； Synergistic effect； Calcium stearate； Zinc stearate PVC广泛应用于工业、建材、农业等领域，在PVC加工过程中，需要添加热稳定剂以提高其抗热解和抗老化等各项性能指标。 传统的PVC热稳定剂主要有铅盐、金属皂、有机锡、有机稀土和钡、锌、镉等。近年来，随着政府对塑料制品，特别是玩具和食品行业制品中重金属含量指标的严格控制，以及人们环保意识的增强和各种法规的不断完善，铅盐稳定剂的应用受到限制，环保型PVC 热稳定剂的开发和应用取得了快速发展。市场出现了各种类型的无毒环保稳定剂，以钙/锌复合热稳定剂多的研究居多。常用的钙皂、锌皂存在初期着色性差和长期稳定性不理想的缺点[1]，需与辅助稳定剂复配使用[2]。Ca / Zn复合热稳定剂的特点是无毒，但稳定体系的效果比含Cd、pb的稳定剂的稳定体系差，因此通常要添加辅助稳定剂来改善其性能。张军[3]、杨云翠[4]等先后研究了硬脂酸