多检测GPC测试二醋片的分子量及其分布和特性粘度-烟草科技.PDFVIP

/TobaccoScienceTechnology /TobaccoChemistry 200 8 10 ( 255 ) GPC , 南通醋酸纤维有限公司技术中心, 江苏省南通市钟秀东路 27 号　226008 :凝胶渗透色谱;二醋酸纤维素 ;分子量分布;特性粘度; :采用凝胶渗透色谱(GPC)/示差 (RI)/小角激光光散射(LALLS)/四毛细管示差粘度(DV)三检测 器联用技术对二醋酸纤维素 (二醋 )的重均分子量(M )、数均分子量 (M )、分子量分布(M /M ) w n w n 和特性粘度 (IV)进行了测试。 结果表明:①采用 GPC/RI/LALLS/DV技术可以准确地测试二醋 的 M、M、M /M 和 IV;②以软木浆和短棉绒为原料生产的二醋 的 M、M 较高、M /M 较宽;③热解后 w n w n w n w n 二醋 的 M /M 变宽, IV降低, 并有裂解分子的聚合现象。 w n :TS472　:B　:1002 -0861 (2008 )10-002 1-04 AnalysisofM olecularW eightanditsDistributionandIntrinsicViscosityofCelluloseDiacetateFlake byGPCwithMultipleDetectors CAO JIAN-GUO andGUHAI-BING TechnologyCenterofNantongCelluloseFibersCo., Ltd., Nantong226008, Jiangsu, China Keyword:sGelpermeationchromatography(GPC);Cellulosediacetateflake;Molecularweightdistribution; Intrinsicviscosity Abstrac:tTheweight-averagemolecularweight(M ), numberaveragemolecularweight(M ), molecular w n weightdistribution(M /M )andintrinsicviscosity(IV)ofcellulosediacetateflakewereanalyzedbyGPC w n coupledwithmultipledetector,s includingrefractometerindex(RI), lowanglelaserlightscattering(LALLS) andfour-capillarydifferentialviscosity(DV).Theresultsshowedtha:t1)M, M, M /M andIVofcellu- w n w n losediacetateflakecouldbedeterminedaccuratelybyGPC/RI/LALLS/DV;2 )theM andM werehigher w n andM /M rangewaswiderforcellulosediacetateflakemadefrom softwoodpulpandshortcottonlinte;r3 ) w n whencellulosediacetateflakewaspyrolyzed, theM /M rangebecamewide,r IVdecreased, andthepyro- w n lyzedpolymerizationmightemerge. 　　 ( ) 。 。 , 、、、 , ,