加压和超临界流体在多孔膜中的渗透-高校化学工程学报.PDF

19 5 No.5 Vol.19 2005 10 Journal of Chemical Engineering of Chinese Universities Oct. 2005 1003-9015(2005)05-0577-06 1 1 1 1 1,2 , , , , (1. , 300072; 2.Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA) HeN CO 2 2 He N2 CO2 TQ028.8 A Permeation of Compressed and Supercritical Fluids through Porous Membranes GAO Xiang1 1 1 1 1, 2 , LIU Li-li , LIU Xiu-feng , ZHANG Bao-quan , LIN Y. S. (1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2. Department of Chemical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA) Abstract: For the permeation of compressed and supercritical fluids through porous membranes, the investigation on major influence factors and process modeling is essential. The permeance of helium, nitrogen and carbon dioxide at various temperature, pressure and pressure difference was measured at first. A new model equation was developed by modifying the two-term dusty-gas model. The variation of viscosity with pressure, especially in the near-critical region where the possible abnormal change of viscosity with pressure may exist, was considered in the model development. The results of experimental measurement and theoretical analyses show that the permeation of helium in porous membrane agrees well with the two-term dusty-gas model due to its minor cha