常温固化免烧结泡沫陶瓷复合材材料的制备及性能 Preparation and Property of Normal-Temperature Solidified and Non-Sintered Foam Ceramic Composites.pdfVIP

2 20()9．NO．1 陶瓷 常温固化免烧结泡沫陶瓷复合材料的制备及性能‘ 冯胜山 刘庆丰 (湖北工业大学机电研究设计院 武汉430070) 摘 要 利用自制的粘结剂．选Itj合适的填料、悬浮剂和减水剂、表面活性剂等附加剂．采用聚氨酯泡沫塑料先驱体挂浆 成形法和常温固化工艺．制备出具有均匀、相互贯通孑L结构的免烧结泡沫陶瓷复合材料．其生产工序简单．生产成本低．同 时由于聚氯酯泡沫塑料载体保留其巾．所以产品韧性好．不易脆断。研究结果表明：随着粘结剂加入量的提高和泡沫塑料 载体孔径的减小，泡沫陶瓷复合材料的抗压强度显著增大．但通孔率明显降低；采用适当浓度的碱液对泡沫塑料进行表面 玫性处理．可显著降低其表面张力．提高表面粗糙度，还能溶解残留的封孔薄膜．从而可增加挂浆量．提高其力学性能；但 随着泡沫塑料载体表面改性处理时间的延长．泡沫陶瓷复合材料的通孔率下降；随着常温固化时间的延长．泡沫陶瓷复合 材料的抗压强度逐步上升；常温固化28d时．其抗压强度基本上达到最大值。 关键词 常温固化 免烧结 泡沫陶瓷 复合材料 制备 性能 and of SolidifiedandNon—SinteredFoamCeramic PreparationPropertyNornlaI—Temperature Composites FcngShengshan，Liu InstituteofMechanical＆，Electronic of Qingfeng(Research＆．Design Engineering．HubeiUniversity ’lcchnology．Wuhan，430070) Abstract：Thestructurenon—sintcredleamceramic are themethodof compositesproducedby polymeric spongecoating-- and solidified，withtheuseofhome—madebinderandsuitable dippednormal—temperature padding．suspendingagent。wa— ter—reducerandsurfactant．’lhe are with three—dimensional and compositespossessedsteady network．simpleprocesses COSt．The arcnot tObrittlefractureasaresultofthe foam of cheap compositeseasy polyurethaneretained．7lhethe range contentofbinderandthesurfacetrcatmcntofthe were urethaneleanl resultsshowedthat invesrigatedemphatically．’lhe thevariableshav