再结晶作用对CaO颗粒干法烟气脱硫反应速率影响的试验研究.PDFVIP

第24 卷 第11 期 中 国 电 机 工 程 学 报 Vol.24 No. 11 Nov. 2004 2004 年11 月 Proceedings of the CSEE ©2004 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2004) 11-0203-05 中图分类号：X77 文献标识码：A 学科分类号：61030 再结晶作用对CaO 颗粒干法烟气 脱硫反应速率影响的实验研究 王世昌, 姚 强, 徐旭常 （热能动力工程与热科学重点实验室，清华大学热能工程系，北京市海淀区 100084 ） EXPERIMENTAL STUDY ON THE EFFECT OF RE-CRYSTAL TO THE DRY FGD REACTION WITH CaO PARTICLES WANG Shi-chang, YAO Qiang, XU Xu-chang ( Key Laboratory of Thermal Science and Power Engineering,Deparpment of Thermal Engineering, Tsinghua University, Haidian District, Beijing 100084, China ) ABSTRACT: Increasing reaction temperature can improve the 脱硫反应速率在 800℃达到最大值。CaO 的制备温度高于 reaction rate of dry FGD with CaO particles to some extend. 800℃时，脱硫反应过程中的再结晶过程会使CaO 的脱硫反 However, the CaO grains in the CaO particles growing fast 应速率在 900℃仍然保持上升趋势。此外，CaSO晶粒的再 4 while the CaO particles remaining at higher temperature for a 结晶过程可以提高CaO颗粒的脱硫反应速率。 long time. The re-crystal process reduced the special area and the porosity of CaO particles during dry FGD reaction process. 关键词: 热能动力工程；烟气脱硫反应；CaO 晶粒； CaSO4 The characteristics of desulfurization reaction with reagent 晶粒； 再结晶；反应速率 grade CaO particles and industrial grade CaO particles were 1 引言 studied systematically with TGA, BET, TEM and other equipments in this paper and the experimental results revealed 以 CaO 颗粒为脱硫剂的烟气脱硫反应比较缓