硅氧烷功能单体对聚羧酸减水剂抗泥性能的影响.docVIP

硅氧烷功能单体对聚羧酸减水剂抗泥性能的影响 张光华 危静 崔鸿跃 陕西科技大学教育部轻化工助剂化学与技术重点实验室 山西省运城市泓翔建材有限公司 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 以丙烯酸 (AA) 、γ-甲基丙烯酰氧基丙基三甲氧基硅烷 (KH570) 、异丁烯聚氧乙烯醚 (HPEG) 为单体, 以过氧化氢 (H2O2) /抗坏血酸 (Vc) 为氧化还原引发体系, 巯基乙酸为链转移剂, 采用水溶液自由基共聚法合成了一种含硅氧烷的聚羧酸减水剂.采用红外光谱、核磁共振氢谱、凝胶渗透色谱 (GPC) 对减水剂进行结构表征, 通过水泥净浆流动度测定其减水性能, 采用X-射线衍射 (XRD) 和透射电镜测定蒙脱土吸附减水剂后的层间距, 采用总有机碳 (TOC) 分析仪测定减水剂分别在水泥和蒙脱土上的吸附量, 探究硅氧烷功能单体对聚羧酸减水剂抗泥性能的影响.结果显示:当减水剂折固掺量为0.2%, 蒙脱土掺量为2%时, 水泥水化1h时的净浆流动度为185mm.分别用纯水和减水剂处理过的蒙脱土的层间距都在1.35nm左右, 层间距没有发生变化, 说明蒙脱土与减水剂仅发生表面吸附.含硅氧烷的聚羧酸减水剂在水泥上的吸附量大于普通的聚羧酸减水剂, 硅氧烷减弱了聚羧酸减水剂在蒙脱土上的吸附. 关键词： 聚羧酸减水剂; 硅氧烷; 蒙脱土; 分散性能; 吸附; 作者简介：张光华 (1962-) , 男, 陕西咸阳人, 教授, 博士生导师, 研究方向:功能高分子材料 收稿日期：2017-10-12 基金：国家自然科学基金项目 The effect of siloxane functional monomer on anti-clay properties of polycarboxylate superplasticizer ZHANG Guang-hua WEI Jing CUI Hong-yue Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology; Shanxi Province Yuncheng Hongxiang Building Materials Co., Ltd.; Abstract： Polycarboxylate superplasticizer modified with siloxane group was synthesized by using free radical copolymerization method and using acrylic acid (AA) , isobutylene polyoxyethylene ether (HPEG) and methacryloxypropyltrimethoxysilane (KH570) as monomers, hydrogen peroxide (H2O2) and ascorbic acid (Vc) as initiators, and thioglycolic acid as the chain transfer agent.The copolymer was characterized by FTIR, 1H NMR and GPC.In order to investigate the effect of siloxane functional monomer on anti-clay properties of superplasticizer, the water reduction performance of the superplasticizer was investigated by fluidity tests.The interlayer spacing of montmorillonite modified with superplasticizer was measured by X-ray diffraction (XRD) and transmission electron microscopy (TEM) .Adsorption of water reducing agents on cement and montmorillonite were measured by Total Organic Carbon (TOC) analyze