20000吨乙胺装置分离系统工艺毕业设计.docx

20000吨乙胺装置分离系统工艺设计辛清炜1，李强2 (1.东北电力大学化学工程学院,吉林 吉林132012; 2.东北电力大学化学工程学院,吉林 吉林132012)摘要：本设计的内容是年产20000吨乙胺装置分离系统装置工艺设计，工艺采用连续精馏的方式，使用四个精馏塔，将乙醇和液氨混合加氢精馏成纯度大于99.5%的乙胺产品。本设计主要对T103塔所给的各个组分的质量分数并经过ASPEN软件模拟，得出各个塔的理论板数和回流比以及工艺条件，得出本套工艺装置的初步数据。同时完成物料衡算、热量衡算、并对乙胺精馏塔进行严格设备计算。对塔的冷凝器、再沸器、回流罐、接塔管和进料泵进行了详细计算和选型。关键词：乙胺；精馏；ASPEN软件；工艺设计Process Design of Separation System of 20000t Ethylamine PlantXIN Qing-wei1 ,LI Qiang2(1.Chemical Engineering College, Northeast Dianli University, Jilin Jilin 132012;2.Chemical Engineering College, Northeast Dianli University, Jilin Jilin 132012)Abstract;The present design is 20000 tons per year ethylamine separation system means plant process design, continuous distillation process using manner, using four distillation column, ethanol and ammonia mixing hydrogenation rectification into purity of more than 99.5% of amine products.The design of the main T103 tower to the various components of the quality score and through the ASPEN software simulation, the theoretical plate of each column and reflux ratio and process conditions, the set of process equipment, the preliminary data. At the same time to complete the material balance, heat balance, and the rectification of the column for strict equipment calculation. The calculation and selection of the condenser, the re boiling device, the reflux tank, the connecting pipe and the feed pump of the tower are calculated in detail. And draw the process flow chart of the control point, the material map, equipment layout and piping layout. Key Words：Ethylamine；Distillation；ASPEN；Process planning1绪论乙胺（Ethylamine），无色极易挥发液体，有氨的气味，本品高毒，呈碱性具有强烈刺激性[1]，能刺激眼、肺、气管、皮肤和排泄系统，能与水、乙醇、乙醚混溶,其蒸气与空气可形成爆炸性的混合物，遇热源和明火都会有燃烧爆炸危险。与氧化剂接触会猛烈反应,其蒸气比空气要重，能在较低处扩散到相当远的地方，遇到火源会着火回燃。用于生产医药、染料、表面活性剂[2]、除草剂、橡胶硫化促进剂和离子交换树脂等。2 生产工艺原理乙醇与氨气，氢气进行催化反应，生成乙胺的生产方法。化学反应方程式：++++3 物料衡算物料衡算是化工设计的计算中最基本、最重要内容之一。在解决设计设备尺寸前要定出所处理的物料量。整个过程或其某一步骤中原料、产物、副产物之间的关系可通过物料衡算确定。因此进行工艺设计时，首先要进行物料衡算，物料衡算物料衡算的理论依据是质量守恒。化工生产基本采用连续化生产，其特点是不间段、稳定的向反应系统或设备投入物料，同时产出相应的物料，设备中某一区