Au catalysis 金催化入门资料.pdf

Reviews A. S. K. Hashmi and G. J. Hutchings DOI: 10.1002/anie.200602454 Gold Catalysis Gold Catalysis** A. Stephen K. Hashmi* and Graham J. Hutchings* Keywords: gold · heterogeneous catalysis · homogeneous catalysis · promoters · supports Angewandte Chemie 7896 2006 Wiley-VCH Verlag GmbH Co. KGaA, Weinheim Angew. Chem. Int. Ed. 2006, 45, 7896 – 7936 Angewandte Gold Catalysis Chemie Catalysis by gold has rapidly become a hot topic in chemistry, with a From the Contents new discovery being made almost every week. Gold is equally e ective 1. Introduction 7897 as a heterogeneous or a homogeneous catalyst and in this Review we attempt to marry these two facets to demonstrate this new found and 2. Hydrogenation 7898 general e icacy o fgold. The latest discoveries are placed within a historical context, but the main thrust is to highlight the new catalytic 3. Reactions Involving Carbon possibilities that gold-catalyzed reactions currently o er the synthetic Monoxide 7903 chemist, in particular in redox reactions and nucleophilic additions to