催化氧化法处理废碱液中硫化物的工程应用研究.docVIP

催化氧化法处理废碱液中硫化物的工程应用研究 何长明 李俊 刘晓晶 陕西省石油化工研究设计院陕西省工业水处理工程技术研究中心 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 近年来, 随着工业的迅猛发展, 环保要求也越来越严格。在环保政策的推动下, 进一步强化了对工业废水的处理要求。废碱液中的硫化物含量高, 对生态环境造成了很大的威胁。本文采用催化氧化法处理陕北某煤化工企业乙烯废碱液中的高浓度硫化物, 介绍了其工艺流程和脱除机理, 在实验室小试实验优选条件的基础上进一步研究了脱硫剂种类、投加量、反应温度、反应时间、曝气量及pH值在工程应用上对硫化物脱除的影响。结果表明:当采用脱硫剂3且其投加量为5‰, 曝气量为7500m3/h, 在60-65℃下反应75h, 硫化物的脱除率为96%。最后对硫化物的转化规律进行了初步的研究。 关键词： 催化氧化法; 废碱液; 硫化物; 脱除率; 作者简介：何长明 (1965-) , 男, 陕西汉中人, 陕西省石油化工研究设计院高级工程师, 从事水处理方面研究。电话:0912-4866441, E-mail:1006947358@ 基金：陕西延长石油 (集团) 有限责任公司科技计划项目 (ycsy2017ky-A-38) 资助 The study on the engineering application of the treatment of sulfide in spent caustic by catalytic oxidization HE Changming LI Jun LIU Xiaojing Shaanxi Industry Water Treatment Research Centre of Engineering Technology, Shaanxi Research Design Institute of Petroleum and Chemical Industry; Abstract： With the rapid development of industry, it is more and more strict of the environmental protection requirements recently. The treatment requirements of industrial wastewater is further strengthened under the promotion of environmental policy. The high sulphide content in the spent caustic poses a great threat to the ecological environment. Catalytic oxidization technology is used for removing sulfide from spent caustic of ethylene cracking and process flow and removal mechanism are introduced in this paper. On the basis of the optimization test in the laboratory experiment conditions, the variety of desulfurizer, dosing quantity, reaction temperature, reaction time, oxygen and p H value are further researched on the removal effect of sulfide on engineering application. It is shown that the removal efficiency of S2- is up to 96% when the dosage of desulfurizer 3 is 5‰, aeration rate is 7500 m3/h, reaction temperature is at 60-65℃ and reaction time is 75 hours. Finally, the transformation rule of sulfide is studied. Keyword： catalytic oxidization; spent caustic; sulfide; removal e