微波消解-ICP-MS法测定土壤中的硒含量.docVIP

微波消解-ICP-MS法测定土壤中的硒含量 刘芸 曹国松 程佩 张冬冬 张一凡 谭芳 杨小秋 胡思前 江汉大学光电化学材料与器件教育部重点实验室 江汉大学化学与环境工程学院 武汉市蔡甸区农业技术推广服务中心 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 采集湖北省武汉市蔡甸区4个不同地块的土壤样品, 利用微波消解法进行前处理, 建立了一种微波消解辅助电感耦合等离子体质谱 (ICP-MS) 法检测土壤中硒含量的方法。确定消解试剂为2mL硝酸、3mL氢氟酸及3mL双氧水;校正曲线的线性范围为1100μg·L-1, 相关系数R2为0.9995;采用土壤形态成分标准物质GBW07445GSF-5进行检测, 结果表明测试平均值在标准值范围内, RSD为4.4%。土壤样品检测结果发现, 硒含量最高的是b区地块, 为1.0702mg·kg-1, 最低的是a区地块, 为0.5807mg·kg-1, 4个地块均达到了富硒土壤的标准。不仅为评价土壤中的硒含量提供了快速、准确、灵敏的检测方法, 也为蔡甸区开发富硒特色农业种植提供了重要的科学参考。 关键词： 硒; 微波消解; ICP-MS; 土壤; 作者简介：刘芸 (1984-) , 女, 湖北利川人, 博士, 讲师, 研究方向:纳米材料;E-mail163.com; 作者简介：胡思前, 教授, E-mail:husiqian@126.com。 收稿日期：2017-06-26 基金：武汉市科技攻关项目 (2014022905011274, IWHS2016216, Determination of Selenium Content in Soil by Microwave Digestion-ICP-MS LIU Yun CAO Guo-song CHENG Pei ZHANG Dong-dong ZHANG Yi-fan TAN Fang YANG Xiao-qiu HU Si-qian Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, Jianghan University; Agro-Tech Extension and Service Center of Caidian; School of Chemical and Environmental Engineering, Jianghan University; Abstract： We collected soil samples from four different areas of Caidian region in Wuhan, Hubei province, which were named as area a, b, c, and d, and used a microwave digestion method to pretreat soil samples.We established a microwave digestion-ICP-MS method for the determination of selenium content in soil.The optimal digestive reagents were 2 mL nitric acid, 3 mL hydrofluoric acid, and 3 mL hydrogen peroxide.The line range of calibration curve was 1100μg·L-1, and R2 was 0.9995.Moreover, we used soil morphologic element standard material GBW07445 GSF-5 for the determination.The results showed that the detected average values were in the range of standard values, and RSD was 4.4%.The maximum value of selenium content in soil was 1.0702 mg·kg-1 from area b, while the minimum value was 0.5807 mg·kg-1 from area a.The soil from four different a