聚乙二醇单硬脂酸酸酯固体脱墨剂的制备及应用研讨.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 聚乙二醇单硬脂酸酸酯固体脱墨剂的制备及应用研究 杨晓武, 沈一丁 ( 陕西科技大学化学化工学院 陕西咸阳 712081) 摘 要:以三硬脂酸甘油脂 聚乙二醇 二乙醇胺为原料 制备一系列表面活性剂 合适反应条件为 140 2h 参考 HLB 值 通过复配制成固体脱墨剂 所得产品具有良好自乳化性 在配方为W (尿素)=3% W(NaSiO )=3%,W(脱墨剂)=0.3% W Na SO 3 2 4 =1%,W 表面活性剂 =0.4% 时 取得较好脱墨效果 通过扫描电镜观察 对回收纤维表面的油墨及其它杂质颗粒具有良好的剥 离清洗作用 关键词: 脱墨剂 HLB 值 非离子表面活性剂 中图法分类号 文献标识码 文章编号 Application and synthesis of a solid deinking agent YANG Xiao-wu SHEN Yi-ding (Chemistry and Chemical Engineering College ,Shannxi University of Science Technology, Xianyang 712081,China) Abstract:The newdeinking agent for recycling of was paper were produced . The result showed this product was a high-performance deinking agent .This agent efficiently removed ink particles from the pulp fiber and the resulting recycled pulp had a high brightness and a low content of residual ink. Efforts were made to find an optimum condition of various surfactants used for high brightness and yield of recycled pulp. In this study, the glycerine tristearate reacted with at polyoxyalkylene at 140 for 2h to prepare various types of general surfactants for deinking. Flotation deinking expts. were conducted in order to examine the effect of various solid-type deinking agents. As a result, an optimum combination of this new solid-type deinking agent, which resulted in high brightness and yield, was m(polyoxyalkylene monostearate) m(stearic acid bis-(2-hydroxy-ethyl)-amide) m[fatty alcohol polyoxyethylene (3) ether] m[Polyoxyethylene(10) octylphenol ether]=2 8 3 7. This new type d