矿物基纳米冷冻机油与HFC制冷剂的相溶性研究.pdfVIP

文章编号：CAR166 矿物基纳米冷冻机油与 HFC 制冷剂的相溶性 1,2 1 2 2 王瑞祥 吴业正 解国珍 邵宗义 (1 西安交通大学 能源与动力工程学院，西安 710049;2 北京建筑工程学院 环境与能源工程学院，北京 100044) 摘 要 通过实验，分别考察了纳米粒子浓度和纳米冷冻机油的制备工艺参数对矿物基纳米冷冻机油与HFC制冷剂的互溶解 度（简称SOR）的影响。结果显示，由正辛醇和含少量Tween-80的Span-80修饰的NiFe O 纳米粒子制备的烷基苯纳米冷冻 2 4 机油在R425a 中的溶解度能够达到15%，接近POE/HFC互溶解度的水平；低浓度时,SOR随纳米粒子浓度的增加而增加，高浓 度时则基本不变,拐点浓度大致在3g/L左右；纳米冷冻机油在制冷剂中的溶解度SO/R随温度的变化规律符合Gaussian方程， 制冷剂在纳米冷冻机油中的溶解度SR/O随温度的变化规律符合Gaussian peak方程,计算结果与实验结果之间的最大偏差小 于9%，满足工程需要。 关键词 互溶解性 相溶性 纳米冷冻机油 HFC制冷剂 纳米粉体 矿物油 Wang Ruixiang1,2 Wu Yezheng1 Xie Guozhen2 Shao Zongyi2 (1School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049; 2 School of environment and Energy Engineering,, Beijing University of Civil Engineering and Architecture, Beijing 100044, Abstract A testing system of the solubility of mixing refrigerant with nano-refrigeration oil was developed. Some factors, such as the concentration of nano-particles in lubricant, the preparing methods of nano-refrigeration oil and the modifying methods of nano-particles on the solubility of Oil/Refrigerant mixture (SOR), was experimentally investigated. The results show that the solubility of R425a in nano-NiFe2O4 alkylbenzene refrigeration oil, in which the nano-NiFe2O4 particles had been modified with n-octanol and Tween-80 that containing a small amount of Span-80, is about 15% (wt/wt), closing to that of the POE/HFC mixture. The solubility of the nano mineral refrigeration oil in HFC refrigerant increases with the concentration of the nano-parti