科技含金量.ppt

问题与讨论 完成论文和投稿 演讲人经历的两个例子 Jin XB, Gao P, Wang DH, Hu XH, Chen GZ, Electrochemical preparation of silicon and its alloys from solid oxides in molten calcium chloride, Angew. Chem. Int. Edit., 43 (2004) 733-736. Wu MQ, Snook GA, Chen GZ, Fray DJ, Redox deposition of manganese oxide on graphite for supercapacitors, Electrochem. Comm., 6 (2004) 499-504. Electrolysis preparation of silicon and its alloys from solid oxides in molten calcium chloride Silicon plays essential roles in the semiconductors industry as well as in solar batteries for its photoelectric-catalysis. The traditional production of silicon is mainly by the carbothermal reduction of silicon dioxide, in which by solid reaction at 1700℃, the oxygen element is took out by the generation of CO2 and metal silicon formed at the same time. By this method, the product can not be very pure for the residual oxygen and the Si-C alloys as impurity. As it was proved that the SiO2 can be directly reduced in the chloride molten salt, a great chance rises for the metal silicon production by electroreduction. Here shows the practical feasibility of the industry production and also a new concept about the metal and metal alloy produced by directly electroreduction of mixed oxides in high temperature molten salts. Recently, Nohira et al. reported that the oxygen can be removed from the bulk SiO2 in a molten CaCl2 electrolyte at 850℃ by pinpoint and bulk electrochemical methods1. The similar results are also obtained in our electrochemical study of the quartz in CaCl2 molten salts. In our study, a W wire with 0.25mm in diameter was sealed in the quartz pipe, after grinded, the end face of the W wire is revealed to the molten salts and the SiO2 glass compactly contacts with the metal tungsten along the W brim as a circle. For the contact between the SiO2 and the electric conductor is very intimate, the cyclic voltammograms peaks are more distinguished2. The reduction of SiO2 begin at -0.85V (vs. Pt in CaCl2). The current