合成苯并三氮唑紫外吸收剂的加氢催化剂研究.docVIP

合成苯并三氮唑紫外吸收剂的加氢催化剂研究 李春梅1，丰枫1，朱宇翔1，张军华2，张群峰1，李小年1* (1.浙江工业大学 工业催化研究所,绿色化学合成技术国家重点实验室培育基地,浙江 杭州 310032;2.浙江常山科润化学有限公司,浙江 衢州 324200) 摘要：文研究了炭载PdPt-Cu三金属催化2-硝基-（2’-羟基-5’-甲基苯基）偶氮苯（HAB）加氢合成2-（2’-羟基-5’-甲基苯基）苯并三氮唑（UV-P）的性能在323 K、0.5 MPa氢气压力条件下反应5 h后HAB转化率为100%、UV-P选择性达92.2%，实现了偶氮化合物加氢高选择性地合成苯并三氮唑紫外吸收剂。利用XRD、TEM及XPS催化剂表征，发现Cu-Pd、Cu-Pt合金相与催化剂表面适量的缺电子态贵金属物种(Mδ+)可以有效抑制N—N键断裂与过度加氢副反应，降低四氢化合物和芳胺类等副产物的生成。 : 苯并三氮唑；Cu掺杂；催化加氢；UV-P 中图分类号：TQ9 文献标识码：A Hydrohenation Catalysts for Synthesis of Benzotriazole Ultraviolet Absorbers LI Chun-mei1, FENG Feng1, ZHU Yu-xiang1, ZHANG Jun-hua2, ZHANG Qun-feng1, LI Xiao-nian1 (1. State-key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Industrial Catalysis Institute, Zhejiang University of Technology, Hangzhou 310032,Zhejiang, China; 2. Zhejiang Changshan Kerun Chemical Co., Ltd, Quzhou 324200, Zhejiang, China) Abstract: Benzotriazole and its derivatives are widely used as UV absorbers, due to their low toxicity and excellent stability. The catalytic performance of Pd-Pt-Cu/C for the synthesis of 2- (2-hydroxy-5-methylphenyl) benzotriazole (UV-P) from 2-nitro- (2-hydroxy-5-methylphenyl) azobenzene (HAB) was studied. The conversion of HAB reached 100% and the selectivity of UV-P kept 92.2% after 5 h at 323 K and 0.5 MPa hydrogen pressure. XRD, TEM and XPS results showed that the formation of Cu-Pd, Cu-Pt alloy phase and the proper amount of the noble metal species (Mδ+) on the surface of the catalyst were the key factors to inhibit the breakage of N—N bond and to reduce the amount of by-product due to excessive hydrogenation, which thereby supressed the formation of tetrahydrofins and aromatic amines by-products. Key words: benzotriazole; Cu-doped; catalytic hydrogenation; UV-P Foundation item 基金项目：国家自然科学基金 作者简介：李春梅（1987-），女，硕士研究生。联系人：李小年，教授，电话：0571E-mail：Xnli@zjut.edu.cn[1-3]。它可以提高聚合材料的稳定性、耐候性及抗衰老性能。 目前，由2-硝基-（2’-羟基-5’-甲基苯基）偶氮苯（HAB）合成2-（2’-羟基-5’-甲基苯基）苯并三氮唑（UV-P）的方法主要有：化学还原法[4-5]、催