§7. Boltzmann Statistics 热力学·统计物理 英文教学课件.pptVIP

§7. Boltzmann Statistics §7.1 The statistics expression of thermodynamics quantities 7.1.1 The statistics expression of internal energy Introduce a new function Z1 called partition function Then With the formula (7.1.1) and (7.1.3) it gets 7.1.2 Generalized work Generalized force performed by environment follows that For instance , In infinitesimal quasi-static process the work performed by environment follows that The total differential of i