气相色谱串联质谱法检测黄芪中二嗪磷残留量的不确定度评定.pdfVIP

6 5 Vol. 6 No. 5 2015 5 Journal of Food Safety and Quality May. , 2015 1* 1 1 2 易大为 , 邹 宇 , 刘 杨 , 高敬红 (1. , 110036; 2. , 110015) 摘 要: 目的 方法 , 结果 4 , 0.016 mg/kg, k=2 0.032 mg/kg, (0.091±0.032)mg/kg结论 , , , 关键词: ; ; ; Evaluation of uncertainty for diazinon residues in Astragali radix by gas chromatography-mass spectrometry method 1* 1 1 2 YI Da-Wei , ZOU Yu , LIU Yang , GAO Jing-hong (1. Liaoning Institute for Drug Control, Shenyang 110036, China; 2. Shenyang Zhiying Pharmaceutical Co., Ltd., Shenyang 110015, China) ABSTRACT: Objective To evaluate the uncertainty for diazinon residues in Astragail radix by gas chromatography-mass spectrometry. Methods The models for evaluation of the uncertainty about both standard work curve and sample quantitative testing were established, and the factors that influenced the measurement were investigated. Results The four main factors were quantized including mobility of standard curve, repetitiveness of testing results extract efficiency of diazinon in Astragali radix, and the volume of internal standard solution. The combined standard uncertainty was obtained as 0.016 mg/kg, the expanded uncertainty was 0.03