OilQuant 定量分析曲线包.ppt

OilQuant 定量分析曲线包for S4 EXPLORER and SRS 3400 油品中24个元素的定量分析 也可以用于固体燃料、塑料、聚合物等样品 S4 EXPLORER - OilQuant 直接液体样品分析 liquid samples can be analysed directly in plastic cups with a thin window of polypropylene, prolene, mylar or similar foils at the bottom the sample area in the spectrometer cannot be evacuated, so this area or the whole spectrometer have to be flushed with Helium foil and He absorb the radiation of the ultra-light elements S4 EXPLORER - OilQuant 使用多套标准样品绘制校准曲线 样品制备 ~ 7.0g 样品放入液体杯中 (外径 ? 4.0cm, 内径 3.5cm), 4μm Prolene 或 2.5μm 聚脂膜作杯底 测量条件 激发: Rh 靶, 1000W 准直器: 0.23°, 0.46° 晶体: LiF(200), PET, OVO-55 探测器: Pro4 封闭正比计数器、闪烁计数器 测量时间: 自动: 峰值和背景分别测量25秒或统计误差 3s ? 1% 校准曲线 使用SPECTRAplus 软件包中的变动 ?系数法 XRF: direct Analysis of Liquid Samples Element Range: Na - U OilQuant:optimized for defined preparation sample: 7,0 ± 0,1 g oil in a liquid cup (inner diameter 3,5cm, 7KP1901-8FA) with the following foils 4μm Prolene (7KP1901-8BG) for oils and diesel and 2.5μm Mylar (7KP1901-8BR) for gasoline and super gasoline S4 EXPLORER:氦气冲洗 及 真空封档 OilQuant S4 EXPLORER 2 种氦气使用模式: 40 l/h 常压: 高挥发性油品 减压（节约氦气模式）:20 l/h 挥发性低的油品 XRF: direct measurement of liquids -OilQuant元素范围 S4 EXPLORER:Parameter-Definitions S4 EXPLORER - OilQuantCalibration: V in Oil: 0 - 500 μg/g S4 EXPLORER - OilQuantCalibration: V in Oil: 0 - 500 μg/g S4 EXPLORER:Calibration and LLDs for Traces in Oils S4 EXPLORER:Calibration and LLDs for Traces in Oils S4 EXPLORER - OilQuantSpecialized: Ferrocen in Diesel Fuel S4 EXPLORER - OilQuant, for example:Ferrocen in diesel fuel S4 EXPLORER - OilQuant, for example: S in gasoline S4 EXPLORER - OilQuantSpecialized: S in Gasoline S4 EXPLORER - OilQuant, for example: Chlorine in Oils S4 EXPLORER - OilQuant, for example: Chlorine in Oils S4 EXPLORER - OilQuant, for example: Mg in Oil: 0 - 900 ppm S4 EXPLORER - OilQuant, for example: Mg in Oil: 0 - 900 ppm S4 EXPLORER - OilQuant:influence of differen