高炉粉尘和转炉尘泥的还原脱锌试验-钢铁钒钛.PDFVIP

第34卷第4期 钢摇 铁摇 钒摇 钛 Vol.34,No.4 2013年8月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 August2013 高炉粉尘和转炉尘泥的还原脱锌试验 巨建涛,党要均,赵忠宇 (西安建筑科技大学冶金工程学院,陕西 西安710055) 摘摇 要:分析了高炉瓦斯泥、布袋除尘灰和转炉污泥三种粉尘的化学组成、粒度组成和物相分布等物化性质。 用热 力学软件Factsage验证了还原脱锌的可行性,并通过TG-DSC试验确定了反应的初始温度。 进而试验考察了还原 气氛、温度、时间、C/ O对粉尘脱锌率和金属化率的影响。 结果表明:粉尘球团可以在弱氧化气氛下进行还原,粉尘 球团的脱锌率和金属化率随温度、时间的增加而升高。 在球团C/ O=1郾1,还原温度为1300 益下还原40 min后,球 团的金属化率大于85%,脱锌率大于95%。 关键词:高炉粉尘;转炉污泥;直接还原;金属化率;脱锌率 中图分类号:X756摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)04-0036-05 DOI:10.7513/ j.issn.1004-7638郾2013郾04郾007 Experimental Study on Dezincification of BF Dust and Converter Sludge by Reduction Ju Jiantao,Dang Yaojun,Zhao Zhongyu (Department of Metallurgy Engineering,Xi爷an University of Architecture and Technology,Xi爷an710055,Shanxi,China) Abstract:Physico鄄chemical properties including chemical composition, particle size distribution and phaseof BFdust,dustcollectedbybag鄄typecollectorandconverter sludgewereanalyzed. Thefeasibility for dezincificationbyreductionwasvalidatedbythermodynamicsoftwareFactsageandtheinitialtempera鄄 ture for the reduction was obtained by TG鄄DSC experiment. Furthermore,the effect of reduction atmos鄄 phere,temperature,time and C/ O ratio on the metallization and dezincification rate of the above鄄men鄄 tioned dustsand sludgewereinvestigated. Resultsshow that dustpelletscanbereducedinweakoxidiza鄄 tion atmosphere,andthedezincificationrateandmetallizationrateofthedustpelletsincreasewiththein鄄 crease of temperature andtime. With C/ Oratio of 1.1,reductiontemperature of 1300 益 andreduction time of40 min,metallizationrateanddezincificationrateofthepelletsarehigherthan85% and95% re鄄 spectively after the