铅和铬污染包气带及再释放规律的实验研究 Study on the migration and release of lead and chromium and in the vadose zone.pdfVIP

中国环境科学 2014,34(9) ：2211~2216 China Environmental Science 铅和铬污染包气带及再释放规律的实验研究 陈子方,赵勇胜,孙家强, 白 静,刘 璐,周 睿* (吉林大学,地下水资源与环境教育部重点实验室,吉林 长春 130021) 摘要：利用有机玻璃柱模拟包气带,研究了 Pb2+和 Cr6+在污染包气带时的迁移转化规律, 以及雨水淋洗受污染包气带中重金属再释放规律. 结果表明:包气带受重金属污染过程中,铅和铬在粗砂包气带中的迁移速率分别为 7.25cm/d 和 0.4cm/d,远大于其在细砂包气带中的迁移速 率 4.46cm/d 和 0.36cm/d,且 Cr2O72-形式存在的六价铬在包气带中的迁移速率比的铅离子迁移速率大 10 倍以上;在模拟实验中,溶液在通过 包气带区域时六价铬还原为三价铬的反应很弱,通过包气带的水样中三价铬未检出,并且包气带介质中三价铬含量(0.006mg/kg)几乎为零; 雨水淋洗铬和铅污染的粗砂和细砂包气带模拟研究中铅淋洗溶出率为 0.056%和 0.112%,铬淋洗溶出率为 62.33%和 40.36%. 因此,Cr2O72-在 砂质包气带中的迁移性很强且容易从介质表面淋洗去除,而铅在介质中的迁移性较差且很难从介质中淋洗去除掉. 关键词：重金属；砂质包气带；迁移转化；再释放 中图分类号：X523 文献标识码：A 文章编号：1000-6923(2014)09-2211-06 Study on the migration and release of lead and chromium and in the vadose zone. CHEN Zi-Fang, ZHAO Yong-Sheng, * SUN Jia-Qiang, BAI Jing, LIU Lu, ZHOU Rui (Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021 China). China Environmental Science, 2014,34(9)：2211~2216 Abstract ：Sand-column simulations were designed to investigate charateristics of migration and transformation of Pb2+ and Cr6+ and their releasing mechanism flushed by rain water in the vadose zone. Experimental results indicated that the migration rate of hexavalent chromium was ten times more than that of lead in the vadose zone; and the migration rate of lead and hexavalent chromium was 7.25cm/d and 0.4cm/d in the coarse sand and 4.46cm/d and 0.36cm/d in the fine sand, respectively. Reduction reaction of hexavalent chromium was not a dominant process in the vadose zone; the trivalent chromium was not detected in the water, and the content was 0.006mg/kg in the vadose media. The removal efficiency of Pb2+ was 0.056% and 0.112%, and Cr O 2- was 62.33% and 40.36% for fine sand and coarse sand columns flushed by rain