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10_【2010 Electrochemical and Solid-State Letters】 NH4AlF4@LCO 4.5V
Electrochemical and Solid-State Letters, 13 8 A101-A104 2010 A101
1099-0062/2010/138/A101/4/$28.00 © The Electrochemical Society
Improved Electrochemical Performance of NH AlF -Coated
4 4
LiCoO2 Cycled over 4.5 V
Rachid Amine,a,* Ho Hyun Sun,b Ho Jin Sun,b and Jai Prakasha,**,z
aCenter for Electrochemical Science and Engineering, Department of Chemical and Biological Engineering,
Illinois Institute of Technology, Chicago, Illinois 60616, USA
b
Glenbrook North High School, Northbrook, Illinois 60062, USA
Cathode coatings are being developed to improve lithium-ion batteries. In this effort, LiCoO particles were coated with NH AlF
2 4 4
by a simple dry-coating process to enhance capacity retention on a 4.5 V cutoff cycling. Compared with pristine LiCoO , this
2
coating greatly improved the electrode cyclability and rate capability. Electrochemical impedance spectroscopy and a cobalt
dissolution test showed that the NH4AlF4 coating protected the LiCoO2
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