10_【2010 Electrochemical and Solid-State Letters】 NH4AlF4@LCO 4.5V.pdf

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10_【2010 Electrochemical and Solid-State Letters】 NH4AlF4@LCO 4.5V.pdf

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10_【2010 Electrochemical and Solid-State Letters】 NH4AlF4@LCO 4.5V

Electrochemical and Solid-State Letters, 13 8 A101-A104 2010 A101 1099-0062/2010/138/A101/4/$28.00 © The Electrochemical Society Improved Electrochemical Performance of NH AlF -Coated 4 4 LiCoO2 Cycled over 4.5 V Rachid Amine,a,* Ho Hyun Sun,b Ho Jin Sun,b and Jai Prakasha,**,z aCenter for Electrochemical Science and Engineering, Department of Chemical and Biological Engineering, Illinois Institute of Technology, Chicago, Illinois 60616, USA b Glenbrook North High School, Northbrook, Illinois 60062, USA Cathode coatings are being developed to improve lithium-ion batteries. In this effort, LiCoO particles were coated with NH AlF 2 4 4 by a simple dry-coating process to enhance capacity retention on a 4.5 V cutoff cycling. Compared with pristine LiCoO , this 2 coating greatly improved the electrode cyclability and rate capability. Electrochemical impedance spectroscopy and a cobalt dissolution test showed that the NH4AlF4 coating protected the LiCoO2