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Low Temperature Pyrocarbon : a review
1,2 1 1 1
Xavier Bourrat *, Francis Langlais , Georges Chollon and Gérard Louis Vignoles
1
Laboratoire des Composites Thermo-Structuraux, Université Bordeaux 1, 3 Allée de la Boétie 33 600
Pessac, France
2
Present adresse : Institut des Sciences de la Terre d’Orléans, Université of Orléans-CNRS,
Geosciences BP 6759, 45067 Orléans Cedex 2, France
Este artigo é uma síntese das pesquisas recentes na área dos pirocarbonos. Pirocarbono é uma
forma de carbono preparada por deposição química em substratos quentes (acima de 900°C)
mediante pirólise de hidrocarbonetos. Aplicações se encontram nas áreas de materiais compósitos
termostruturais, de reatores nucleares ou de biomateriais. Muito recentemente, um avanço importante
foi cumprido na compreensão dos processos de crescimento. Uma classificação dos pirocarbonos de
baixa temperatura é apresentada ; ela se fundamenta na medição da quantia de defeitos e do grau de
anisotropia, fazendo uso da espectroscopia Raman. Traz um relacionamento bem esclarecido entre
mecanismos de crescimento, estrutura e propriedades dos pirocarbonos.
This article is a synthetic survey of the recent researches in the field of pyrocarbons. Pyrocarbon is the
form of carbon which deposits on hot surfaces above 900°C by cracking of hydrocarbons. Applications
are in the fields of composite materials, nuclear reactors or biomaterials. Very recently, an important
step was reached concerning the understanding of the growth processes. A classification of the low
temperature pyrocarbons is introduced. It is based on the measure of carbon defects and anisotropy,
using Raman spectroscopy.
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