Membrane Extraction Ion Mobility Spectrometry for in Situ Detection of Chlorinated Hydrocarbons in Water英文文献.pdfVIP

Anal. Chem. 2010, 82, 4089–4096 Membrane-Extraction Ion Mobility Spectrometry for in Situ Detection of Chlorinated Hydrocarbons in Water Yongzhai Du,† Wei Zhang,† William Whitten,† Haiyang Li,‡ David B. Watson,† and Jun Xu*,† Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831 and Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 Membrane-extraction ion mobility spectrometry (ME-IMS) Ion mobility spectrometry (IMS) technology as a field-deploy- has been developed for in situ sampling and analysis of able vapor analyzer has been used for detecting chemical warfare trace chlorinated hydrocarbons in water in a single agents, toxic industrial compounds, and trace explosives. It is of procedure. The sampling is configured so that aqueous great interest to use IMS as a field-deployable sensor for contaminants permeate through a spiral hollow poly(dim- monitoring trace chlorinated solvents. Previously, GC-IMS has ethylsiloxane) (PDMS) membrane and are carried away been used for ex situ analysis of contaminated water.1-3 GC- by a vapor flow through the membrane tube. The extracted differential ion mobility spectrometry (DMS) has been studied analyte flows into an atmospheric-pressure chemical- for detecting halocarbons in the vapor phase.4 In 2006-2007, Kanu ionization (APCI) chamber and is analyzed in a specially et al.5 and Sevier et al.6 reported a subsurface IMS for detecting made IMS analyzer. The PDMS membrane was found to soil-gas chlorinated hydrocarbons. Different from mass spectrom- effectively extract chlorinated hydrocarbon solvents from etry (M