以二次再结晶法资源化含硫飞灰废弃物-中国鑛冶工程学会互动式网站.PDF

以二次再結晶法資源化含硫飛灰廢棄物* Recycling of sulfur bearing waste ashes by Recrystallizations* 1 2 3 3 1 2 3 4 P.S. Tsai , C.Y. Wang , L.J. Gao , C.H. Wu This study intends to develop a recrystallization technology that can reclaim the waste ashes. We used two recrystallization processes to reclaim the waste ashes. We conducted fir st recrystallization ex p er i m en t s t o i nv e st ig at e t h e ef fe ct of r at e of descending temperature on the purity, yield and time of recrystallization . The crystallization products from the fir st crystallization were subj ected to the second recrystallization. Experimental results showed that the rate of descending temperature adopted in our experiments achieved a high purity sodium sulfate (Na SO ) above 2 4 90% 90% and yields of 30%~40%. The second crystallization 30%~40% brought the purity and yield of the sodium sulfate above 99 % and 60 %, respectively. 1 The waste solutions of the recrystallization processes 99% 60% were analyzed by iodine titration method. Experimental results showed that the concentration of sodium sulfite (Na SO ) in the waste solution s was above 70%. The 2 3 waste solutions of the recrystallization processes are good 70% candidates for recycling the sodium sulfite. Key wo