有机改性碳纤维氟橡胶复合材料摩擦磨损性能研究.doc

有机改性碳纤维/氟橡胶复合材料摩擦 磨损性能研究 II闫普选王玉峰王梦沂韩飞雪 桂林电子科技大学材料科学与工程学院 利用液相氧化法对碳纤维（CF）进行表面刻蚀，并采用硅烷偶联剂K11570对CF 进行表而改性，将CF、酸改性碳纤维（aCF）及有机改性碳纤维（oCF）作为填 料分别添加到氟橡胶（FKM）基体中，采用机械共混法制备QVFKM复合材料， 分别对复合材料硫化性能、硫化后压缩永久变形性能及摩擦磨损性能进行表征， 研宄CF改性前后性能的变化及改性方式对性能的影响。采用扫描电子显微镜分 析CF的微观形貌。结果表明，CF的添加可以提高FKM复合材料的硫化速率和交 联密度、压缩永久变形性能。在300r/min转速下，载荷在10N到70N变化时，以 及在50N载荷下，转速在100r/min增加到500r/min时，有机改性CF/FKM的摩 擦系数和磨损率最小，相比纯FKM，有机改性后的碳纤维使FKM耐磨性能最高提 升1. 2倍。 关键词： 氟橡胶;碳纤维;偶联剂改性;摩擦磨损; 陈丁（1990-）,男，，从事功能高分子材料加工及成型研究。 2016—06-24 Study on friction and wear property of organic modified carbon fiber/fluorine rubber composite Chen Ding Yan Puxuan Wang Yufeng Wang Mengyi Han Feixue School of Materials Science and Engineering, Guilin University of Electronic Technology; Abstract： Carbon fiber (CF) was treated in the method of liquid-phase oxidation, The surface of carbon fiber was modified by silane coupling agent KH570. The carbon fiber, acid-modified carbon fiber and organic modified carbon fiber as filler were added to the fluorine rubber. Carbon fibcr/fluorinc rubber composites were prepared by mechanical blending method. The curing properties, compressive permanent deformation properties and friction and wear properties of composites after cure were characterized. The changes in carbon fiber performance before and after modification and the effect of modification methods were studied. Scanning electron microscope was used to characterize the surface morphology of composite material. The results showed that the addition of carbon fiber could improve the curing rate, crosslinking density and compressive property of composites. Under 300 r/min speed and load ranging from 10 N and 70 N, and under the load of 50 N, speed ranging from 100 r/min to 500 r/min, the friction coefficient and wear rate of oCF/FKM was minimum. Compared to pure fluorine rubber, organic modified carbon fiber lifted the wear resistance of fluorine rubber over 1. 2 times. Keyword： fluorine rubber; carbon fiber; organic modification of coupling agen