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Automated System for Combinatorial Synthesis and High-throughput(PPT-44)文档
Automated System for Combinatorial Synthesisand High-throughput Characterization ofPolymeric Sensor Materials Application in development and optimizing of sensors for gaseous hydrogen chloride (cable fire alarms) Valentin Kulikov Munich 2004 Introduction to conducting polymers Electropolymerization concept and its realization Measurement concept and its realization Data analysis of experiment Influence of temperature to experiments Optimal thickness of polymer layer Representative results on HCl sensor based on aniline derivates Conclusion Outlook, application range of conducting polymers Four point technique eliminates contact effects allows measurement of bulk polymer conductance To have ossibility to involve four point technique the special topology of electrode sis required Now I wauld like to return and show haw the four point interdigital electrode was developed. lets consider standard four trip structure. If you are folding these strips you will get the most effective using of the surface area. The application of four point technique gives possibility to measure also by two point technique simultaneously. The simultaneous 2 - and 4- point cnductance meausrement is outlined on the right. As you can see the constant voltage is applied on the outer electrodes by voltage source contrelled by feedbyck from voltmeter V2 and current I is measured. Thius the conductance measured by two point technique is given by the contributio of I nad V2. Simultaneously the potential drop betwen inner electrodes is measured, thus the conductivity by four point technique is given as an contribution of I and V4. Taking into accont the distribution of resistances acrooss the model the ratio between G4 and G2 is approximatelly 3 The blosk diagram of the measurement set-up is presented on the current slide. - as you can see the same..., only addit...the 4A switch configuration involved in the multiplexer allows to use four-point measurement technique the multiplexer has implem
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