pH值对水热合成氧化锌粉体形貌及光催化性能的影响.DOCVIP

pH值对水热合成氧化锌粉体形貌及光f{ 化性能的影响 周涛艾建平陈智琴汪细平周泽华张奎姜佳丽 李文魁 江西科技师范大学江西省材料表面工程重点实验室 以Zn （N03） 2*6H20为原料，NaOH为矿化剂，柠檬酸为表面活性剂，在pH值为 8. 0-12.0的条件下采用水热法成功制备出氧化锌纳米粉体。采用X射线衍射 （XRD）、扫描电子显微镜（SEM）、紫外-可见漫反射光谱（DRS）、低温氮吸附、 傅里叶红外光谱（FT-IR）等手段对样品物相、形貌、能带间隙、比表面积和稳 定性进行表征。以样品对15 mg/L的甲基橙溶液的光催化降解性能为评价指标。 结果表明，样品对甲基橙的光催化降解反应为表观一级反应，pH值为12 （无柠 檬酸）时，样品的光催化性能最佳，在300 W高压汞灯照射2 h时甲基橙降解率 达到99%。另外，pH值对ZnO粉体的物相、形貌及光催化性能均有较大影响，p 11=8.0时合成的粉体比表面积较大，但结晶程度差，劣化其光催化性 能;pH=12. 0 （无柠檬酸）时合成高结晶度的六方纤锌矿结构的ZnO粉体，比表而 积为8. 99 m2 ? g 1，光催化性能优异。 关键词： 氧化锌;pll值;水热合成;光催化; 基金：国家自然科学基金 Effect of pH Value on Synthesis of ZnO Powders by Hydrothermal Method and its Photocatalytic Properties ZHOU Tao AI Jianping CHEN Zhiqin WANG Xiping ZHOU Zehua ZHANG Kui JIANG Jiali LI Wenkui Jiangxi Key Laboratory of Surface Engineering， Jiangxi Science and Technology Normal University; Abstract： Zinc oxide nano-powder was prepared by hydrothermal method using zinc nitrate hexahydrate, sodium hydroxide and citric acid by altering the pH of the suspension. The phase, morphology，band gap, specific surface area and stability of ZnO nanorods were studied by X ray diffraction (XRD)， scanning electron microscopy (SEM) and UV-Vis diffuse reflectance spectroscopy (DRS) ， low-temperature nitrogen absorption and fourier transform infrared spectrometer (FT-IR) . The photocatalytic properties of different ZnO samples were studied using an ultraviolet lamp as illumination device and 15 mg/L methyl-orange as stimulant pollutant. The results indicate that, the photocatalytic degradation reaction of methyl orange is first order reaction, when the pH=12 (No citric acid) , excellent photocatalytic activity of the ZnO powders (2 h, degradation rate reach 99%) under 300 W high pressure mercury 1 amp. Tn addition, the pH value has a great influence on the phase， morphology and photocatalytic properties of ZnO powders. Although the specific surface area of the as-prepared powders was largest in pH about 8， the poor degree of crystallinity worsen its photo