SiTixSiy复合物的合成及其锂离子电池负极性能研究.DOCVIP

Si/TixSiy复合物的合成及其锂离子电 池负极性能研究 张文婷汤兑海霍启升 沈阳师范大学化学化工学院能源与环境催化研宄所 吉林大学化学学院无机合成与制备化学国家重点实 验室 通过机械球磨和高温热处理合成得到Si和TixSiy纳米颗粒复合物Si/TixSiy,并 对该化合物进行X射线能谱（EDX） 3射线衍射（XRD）、透射电子显微镜（TEM） 和扫描电子显微镜（SEM）表征.合成的Si/TixSi.和机械球磨的Si/Ti02都被用 于锂离子电池的负极材料，Si/TixSiy表现出优越的充放电性能、较好的循环稳 定性和倍率性能. 关键词： 硅化钦;硅负极;锂离子电池;机械球磨;Si/TixSiy复合材料; 汤兑海， 基金：国家自然科学基金青年科学基金资助项0 Improved performance of Si/TixSiy composite as anode for rechargeable Li-ion batteries ZHANG Wen-ting TANG Dui-hai HUO Qi-sheng Institute of Catalysis for Energy and Environment， College of Chemistry and Chemical Engineering, Shenyang Normal University; State Key Laboratory of Inorganic Synthesis and Preparative Chemistry， College of Chemistry, Jilin University; Abstract： Titanium silicide (TixSiy) was utilized to enhance the electrochemical properties of Si as a promising anode for Li-ion batteries. The Si/TixSiy composite, composed of Si with TixSiy nanoparticles, was synthesized by mechanical milling and annealing at high temperature. The obtained Si/TixSiy composite were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy- The electrochemical properties of the Si/TixSiycomposite and mechanically milled Si/Ti02 as anodes for Li-ion batteries were both investigated. The Si/TixSiy composite showed superior performance compared with the Si/TiO2 sample, including increased initial coulombic efficiency， enhanced rate capability， and better capacity retention. Keyword： titanium silicide; silicon anode; lithium-ion batteries; mechanical milling; Si/TiO2 composite; 0引言 具有高比容量的锂离子电池(LIBs)是便携式电子设备中十分重耍的部件 由于硅基材料的比容量(4 200mAh/g)比商业化石墨(372mAh/g)高，因而具 有更广泛的应用前景，然而，充放电过程中体积显著膨胀￡±±1会导致硅电极材 料容量的快速衰减.体积膨胀增加的压力会导致导电基体的破坏和硅的断裂，从 而降低电极的导电性.[7-9]而且电极和电解液之间的反应也会导致固体电解质 界面膜(SE1)的形成，从而导致硅电极化学性质的退化.[10-11]更重耍的是在 充放电过程中，硅表面的二次暴露会促使更多SEI的形成，导致容量的持续下 降.[12-14] 为了克服以上问题，人们为提高硅负极材料电化学性质做了很多努力.[15-17] 硅化钛(TixSiy)具有较高的导电性和热稳定性，当与硅纳米粒子结合时，表现 出优越的锂离子电池性能.[18-21]例如，Park等