基于锌负极的混合水溶液电池的构建及电化学性能研究.docVIP

基于锌负极的混合水溶液电池的构建及 电化学性能研究 吕世强尚金艳吴贤文李叶华于小林杨沅达 吉首大学化学化工学院 向电解液屮加入明胶、硫脲和硼酸，采用电解的方法制备丫锌箔。采用X射线衍 射仪和扫描电子显微镜对商业锌箔和自制锌箔进行了结构和形貌表征，研宂了 2种锌筘在1 mol/L ZnSO,和2 mol/L Li2S0r混合电解液中的耐腐蚀性能，考察 了 2种锌箔在混合水溶液电池中的循环性能及浮充性能。结果表明，自制锌箔表 面平整光滑，其腐蚀电流为79. 926 uA,电池循环100次后，容量保持率高达 86. 1%,且高温浮充24 h，浮充电流密度仅为3.99 mA/g,自制锌箔耐腐蚀性能 良好。 关键词： 水溶液电池;锌负极;电化学性能;腐蚀性能;浮充; 基金：湖南省教育厅优秀青年项目（15B190） Study on the Construction and Electrochemical Performance of the Aqueous Rechargeable Battery Based on Zinc Anode LO Shi-qiang SHANG Jin-yan WU Xianien LI Ye-hua YU Xiao—1in YANG Yuan-da College of Chemistry and Chemical Engineering, Jishou University; Abstract： In the test, zinc foils were firstly prepared by adding gelatin, thiourea and boric acid into the electrolyte during electrowinning, and the as-prepared zinc foils and commercial zinc foils were characterized by using X-ray diffraction, scanning electron microscopy for investigating their structure and morphology. The corrosion resistance of two kinds of zinc foils in a mixed electrolyte composed of 1 mol/L ZnSOi and 2 mol/L Li2S04 was investigated. And the cycling performance and float charging performance of this hybrid aqueous battery with two different zinc foils were discussed as well. Results showed that the as-prepared zinc foil with a flat and smooth surface had the corrosion current of 79. 926 u A. The capacity retention rate was up to 86- 1% after 100 cycles, and the float charging current density was only 3. 99 mA/g even after 24 h of float charging at a high temperature, indicating the as-prepared foils with a good corrosion resistance. Keyword： aqueous rechargeable battery; zinc anode; electrochemical performance; corrosion resistance; float charging; 水溶液锂离子电池组装工艺简单，且具有安全无毒、成木低廉、倍率性能好等优 点，在大型储能和动力电池领域具有广阔的应用前景［1-4］。 近年来，研究较多的水溶液二次电池体系主要有Li Fe P04/C、Li Mn204/Ti P207、 Li Mn204/ (LixV205/Ppy)、Li Co 02/Ppy等［5-8］ o但以上体系所涉及到的负极 材料容量晋遍偏低，导致电池循环性能较差。2012年，Chen等M首次报道了一 种在弱酸性体系下可充电的混合水溶液电池Li Mn2O4/Zn (简称Re HAB体系)。 该电池经过1 000次循环后，容量保持率仍然高达90%。随后，IJ Fe P04/