[工学]材料概论课件.ppt

The Definition of composite 1. It is manufactured.(人造) A composite is a combined material created by the synthetic assembly of two or more components a selected filler or reinforcing agent and a compatible matrix binder (i.e., a resin) in order to obtain specific characteristics and properties. 2. It consists of two or more physically and/or chemically distinct, suitably arranged or distributed phases with an interface separating them.(两种或两种以上的物理、化学性质不同的物质组成) The components of a composite do not dissolve or otherwise merge completely into each other, but nevertheless do act in concert. 3. It has characteristics that are not depicted by any of the components in isolation.(单一材料不具备的功能) 　 composite(复合材料)=reinforcement(增强材料)+matrix(基体)　 example 骨头bone collagen胶原质 apatite磷灰石 玻璃钢FRP fiberglass玻璃 resin树脂　 混凝土concrete sand沙 cement水泥 7.2. Surface Treatment of Reinforcing Materials  Purpose: Surface treatment is done to improve the adhesion of fillers and fibers to matrix resin by modifying the surface of the solid.改善增强材料的表面，增加与基体的结合 Methods: chemical, plasma, corona discharge and flame treatments 化学、等离子、电晕放电、火焰等 A.? Glass Fibers inorganic fillers Coupling agent (偶联剂)——同时与基体和增强材料 ?(A compound with dual property) In order to improve adhesion at the interface, compounds with dual property, i.e. molecules having chemical functionalities similar to the fiber and the matrix resin, are used 　 Function adhesion promotion protecting fiber surfaces prevent inhibition of polymerization by the solid surface The Usage of Coupling Agent A typical loading level of coupling agent ranges from a small fraction of a percent to a few percent based on the weight of the fiber or filler. The coupling agent may be added to the filler as a neat liquid, an organic solution (有机溶液）, or an aqueous solution (水溶液）. 硅烷偶联剂：结构特征硅烷偶联剂是一类分子中同时含有两种不同化学性质基团(有机官能基团和可水解基团)的硅烷,其经典产物可用通式(ＹＲ)ｎＳｉＸ4-ｎ表示(ｎ=1,2)。式中ＹＲ为非水解有机基团,Ｙ包括链烯基以及末端带有官能团的烃基;