同位素稀释电感耦合等离子体质谱测定环境和生物样品中的.pdfVIP

29 5 V o l. 29, N o. 5 20 10 9 ENV IRONMENTA L CH EM ISTRY Septem ber 2010 1, 2, 3 1, 3 3 2, 3 2, 3 荆 淼 陈诚祥 张建平 庄峙厦 王小如 ( 1. , , 20000 1 2. , , 26606 1 3. , , 36 1005) ( ICPM S) , ( IDICPM S) . ( ICPM S) . , , . . , ICPM S, Cd. , ICPM S. ICPM S . ( IDICPQM S) , , , , . 1 1. 1 A g ilent 7 500 ce( A g ilent) MKII ( ) M iniQ . - 1 112 1000 mg l Cd : Cd: ( 18Mcm ) : M illiQ . . ( GBW 007 605) , ( GBW 074 23) ( G BW 0910 1) . 10% 24h . 1. 2 : - 1 10ngm l L iYCeT l. 1. 1 ICPM S 1200W 0. 8mm 65mm 1. 0 m l m in- 1 - 1 16. 0 Lm in - 1 3 1. 00 Lm in - 1 1000 1. 00 Lm in , 10m s 1. 0 mm 3 1. 3 , 10% HNO 1h . 3 : 0. 25g 50m l, 5 : 9 87 112 Cd, 5m l, 10m in, , 50m l. : 0. 15g 50m l, 112 Cd, 4m l1m l H C lO 1m l HF. 10m in, ,